Surya Biru Murni Acetylene

SBM PRODUCTS

LIQUID NITROGEN

Plant Capacity 700 Liters/Hours
Purity = 99.999%
Impurities < 5> Pressure 0.2 Mpa

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

INDUSTRI GAS ACETYLENE - OXYGEN - NITROGEN - ARGON - DLL

LEMBAR DATA MATERIAL untuk KESELAMATAN (MSDS)

Nitrogen, cair MSDS No. 204

1. IDENTIFIKASI BAHAN

NAMA PRODUK PENGGUNAAN

Liquid Nitrogen (Nitrogen Cair) - Industri minuman & makanan.

- Industri kimia.

- Untuk pendingin.

PABRIK PEMBUATAN - Untuk kesehatan/pengobatan.

1. Surya Biru Murni Acetylene - Untuk dijadikan gas nitrogen.

Jl Mulawarman RT 024 No 70, Batakan KM 18

Kal-Tim Indonesia

Telp : (0542) 743555

Fax : (0542) 763200

Email : sbma@suryabiru.co.id

Website : www.suryabiru.com

2. KOMPOSISI BAHAN

DATA FISIK

Simbol Kimia N₂

Berat Jenis gas Relatif (Udara = 1) 0,967

Titik Didih -195,8^oC

Suhu kritis -146.9 ^oC

Tekanan Kritis 3399 kPa abs. Densitas Kritis 314.9 kg/m³

Berat cairan (@ 101,3 kPa & - 195.8^oC) 808.5 kg/m³

Daya Larut dalam air (@ 101,3 kPa & 0^oC) 0,023 cm³/cm³

Densitas @ 101,3 kPa & - 195.8^oC) 808.5 kg/m³

Titik Bakar tidak terbakar

SPESIFIKASI

Nitrogen >99,9%

Kelembaban <100>

Klasifikasi gas Tidak terbakar

Kelas & sub resiko 2,2

UN No. 1977

3. IDENTIFIKASI BAHAYA

BAHAYA-BAHAYA TERHADAP KESEHATAN

Karena bentuk dan sifatnya nitrogen cair yang sangat dingin ( < - 190 "C), sangat berbahaya bila terkena Organ pada organ tubuh kita , mengakibatan luka bakar dingin. Menghirup Nitrogen yang berkonsentrasi tinggi berbahaya bagi pernafasan. Pada konsentrasi yang sangat tinggi dapat menyebabkan kehilangan kesadaran dan bahkan kematian.

Bahaya lain cairan ini adalah dapat membuat tekanan tinggi gasnya pada ruang tertentu(tetap) karena evaporasi cairan 1 liter bisa menjadi lebih dari 700 liter, sehingga tekanan akan menjadi lebih besar 700 kali .

4. TINDAKAN PERTOLONGAN PADA KECELAKAAN (P3K)

PERTOLONGAN PERTAMA PADA KECELAKAAN

Bila korban sadar :

- pindahkan ke daerah terbuka yang tidak terkontaminasi agar dapat menghirup udara segar

- jaga agar tetap hangat dan tenang

- hubungi dokter bila korban tidak sadar

- pindahkan ke daerah yang tidak terkontaminasi dan berikan bantuan pernafasan bila telah dapat bernafas kembali, lakukan seperti di atas. Tindakan selanjutnya harus dilihat dari gejala dan pendukungnya.

5. TINDAKAN PENANGGULANGAN KEBAKARAN

KEBAKARAN

Nitrogen cair tidak dapat terbakar.

Bila terjadi kebakaran ditempat kerja ,pindahkan barang-barang yang secara tidak langsung terpengaruh api ketempat yang aman, bila perlu siramkan air untuk pendingin Hubungi pemadam kebakaran.

6. TINDAKAN MENGATASI KEBOCORAN DAN TUMPAHAN

KEBOCORAN

Hentikan kebocoran bila memungkinkan.

Kosongkan tempat disekitarnya dari arah pergerakan gas. Bila kebocoran tidak dapat dihentikan, isolasi daerah bejana tekan (tangki) dan beri tanda peringatan.

Bila perlu hubungi PT Surya Biru Murni Acetylene.

7. PENYIMPANAN DAN PENANGANAN BAHAN

PENYIMPANAN BEJANA TEKAN

HAL HAL YANG PERLU SEBELUM DIGUNAKAN

Bejana tekan/tangki penampung harus disimpan di tempat Tangki & krannya tidak boleh terkena minyak atau sejuk dan berventilasi, jauh dari sumber-sumber panas gemuk. Buka/tutup kran -kran perlahan-lahan.

atau material yang mudah terbakar. Pastikan kandungan oksigen ditempat kerja normal, Lindungi tangki ; terutama bagian krannya, lebih dari 19 %. ( 19 ~ 21 %) dan berventilasi baik, dari kerusakan fisik baik dalam keadaan penuh atau kosong. agar tidak terjadi akumulasi dengan cairan gas tsb.

Periksa apakah bejana tekan/tangki telah berlabel.

Tutuplah kran -kran pemakaian jika tangki kosong.

8. ALAT PELINDUNG DIRI (APD)

ALAT PERLINDUNGAN DIRI (APD)

Orang-orang yang pekerjaannya berhubungan dengan penanganan cairan karbon dioksida harus dilengkapi dgn:

- sepatu safety

- sarung tangan kulit (Cryogenic gloves)

- masker untuk pelindungan muka/mata.

9. SIFAT - SIFAT FISIKA DAN KIMIA

URAIAN & SIFAT-SIFAT

Nitrogen cair adalah cairan yang terbentuk dari gas nitrogen yang dicairkan (didinginkan).

Nitrogen cair tidak berwarna, tidak berbau, dan tidak dapat terbakar. Nitrogen lebih ringan dari udara..

Kemasan cairan dikemas dalam tangki vakum atau berisolasi , yang dimiliki PT Surya Biru Murni Acetylene adalah ukuran dari 175 liter dan 5000 s/d 9000 liter.

10. STABILITAS DAN REAKTIFITAS BAHAN

REACTIVITY

Stabil pada suhu dan tekanan normal.

INCOMPATIBILITIES logam, bahan pengoksidasi

Kondisi yang harus dihindari : Lindungi dari kerusakan fisik dan panas. Wadah dapat pecah atau meledak jika terkena panas, hindari kontak dengan air atau uap air.

HAZARDOUS DECOMPOSITION : Thermal decomposition products: oxides of nitrogen, POLYMERIZATION: Will not polymerize.

KETAHANAN MATERIAL

Nitrogen tidak menyebabkan karat sehingga semua jenis metal dapat dipergunakan asalkan peralatan dirancang untuk tahan terhadap tekanan dan suhu yang rendah.

11. INFORMASI TOKSIKOLOGI

Not available

12. INFORMASI EKOLOGI

Not available

13. PEMBUANGAN GAS / DISPOSAL

PEMBUANGAN GAS

Buanglah sisa cairan dengan mengevaporasikan menjadi gas keudara secara pelan-pelan dan hati hati , pada ruangan terbuka dan jauhkan dari orang/pekerja.

Hati hati dengan aliran yang besar , suara yang bising. dan suhu cairan yang sangat dingin.

14. PENGANGKUTAN BAHAN

Menurut department transportasi indonesia material ini termasuk dalam golongan gas bertekanan tinggi yang di simpan dalam bejana tekan dan material ini termasuk material yang tidak terbakar .

Nama pada proses transportasi : Nitrogen, Refrigerated Liquid

UN Number : UN1977

Class Number : 2.2 (Non Flamable)

Packing Group : Non Flamable

15. INFORMASI PERATURAN PERUNDANG-UNDANGAN YANG BERLAKU

Regulasi RI :

Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .
Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .
Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah Bahan Berbahaya dan Beracun.
Kepmenaker RI No. Per-0/Men/1982 tentang pelayanan penyelengaraan Kesehatan Tenaga Kerja.
SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

U.S. REGULATIONS:

CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated.

SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated.

SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21):

ACUTE : Yes

CHRONIC : No

FIRE : No

REACTIVE : No

SUDDEN RELEASE : Yes

SARA TITLE III SECTION 313 (40 CFR 372.65) : Not regulated.

OSHA PROCESS SAFETY (29CFR1910.119) : Not regulated.

16. INFORMASI LAIN YANG DIPERLUKAN

INFORMASI TAMBAHAN

Informasi, rekomendasi dan data yang ada di lembaran ini bertujuan untuk memberikan petunjuk dasar kepada pengguna gas-gas PT Surya Biru Murni Acetylene demi keselamatan pengguna dalam menangani dan menggunakan gas-gas tersebut.

Lembar Data Material untuk Keselamatan (MSDS) untuk gas-gas dan gas-gas campuran yang dikirim oleh PT Surya Biru Murni Acetylene juga tersedia.

Sangatlah penting demi keselamatan pengguna gas-gas tersebut agar orang-orang yang menangani gas tersebut terlatih dengan baik dan benar-benar mengerti kemungkinan bahaya-bahaya yang dapat terjadi.

Informasi dan saran lebih lanjut mengenai hal-hal yang berhubungan dengan penanganan atau penggunaan yang aman dari produk-produk ini dapat diperoleh di kantor-kantor PT Surya Biru Murni Acetylene terdekat.

LIQUID OXYGEN

Plant Capacity 550 Liters/Hours
Purity > 99.6%
Pressure 0.16 Mpa

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

INDUSTRI GAS ACETYLENE - OXYGEN - NITROGEN - ARGON - DLL

MATERIAL SAFETY DATA SHEETS (MSDS)

Oxygen, refrigerated liquid MSDS No. 205

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Oxygen, refrigerated liquid

CAS No : 7782-44-7

Formula : O?

Other means of identification : Oxygen (cryogenic liquid), Liquid Oxygen, Medipure Liquid Oxygen

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Medical applications

Industrial use

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification

Ox. Gas 1 H270

Compressed gas H280

2.2 Label elements

GHS-US Labeling :

Hazard pictogram (GHS-US)

GHS03 GHS04

Signal word (GHS-US) : DANGER

Hazard statements (GHS-US) : H270 - MAY CAUSE OR INTENSIFY FIRE; OXIDIZER

H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED

CGA-HG13 - COMBUSTIBLES IN CONTACT WITH LIQUID OXYGEN MAY EXPLODE ON IGNITION OR IMPACT

Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood

P220 - Keep/Store away from combustible materials, clothing

P244 - Keep reduction valves/valves and fittings free from oil and grease

P271+P403 - Use and store only outdoors or in a well-ventilated place

P282 - Wear cold insulating gloves/face shield/eye protection. cold insulating gloves, face shield, eye protection

P370+P376 - In case of fire: Stop leak if safe to do so

CGA-PG05 - Use a back flow preventive device in the piping

CGA-PG20+CGA-PG10 - Use only with equipment of compatible materials of construction and rated for cylinder pressure

CGA-PG22 - Use only with equipment cleaned for oxygen service CGA-PG24 - DO NOT change or force fit connections

CGA-PG28 - Avoid spills. Do not walk on or roll equipment over spills

CGA-PG06 - Close valve after each use and when empty

CGA-PG23 - Always keep container in upright position

2.3. Other hazards

Other hazards not contributing to the classification

Breathing 80 percent or more oxygen at atmospheric pressure for more than a few hours may cause nasal stuffiness, cough, sore throat, chest pain, and breathing difficulty. Breathing oxygen at higher pressure increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause lung damage and central nervous system (CNS) effects, resulting in dizziness, poor coordination, tingling sensation, visual and hearing disturbances, muscular twitching, unconsciousness, and convulsions. Breathing oxygen under pressure may cause prolongation of adaptation to darkness and reduced peripheral vision.

Contact with liquid may cause cold burns/frostbite.

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name

Product identifier

Oxygen, refrigerated liquid

(Main constituent)

(CAS No) 7782-44-7

100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove victim to uncontaminated area. Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.

First-aid measures after skin contact : The liquid may cause frostbite. For exposure to liquid, immediately warm frostbite area with warm water not to exceed 105°F (41°C). Water temperature should be tolerable to normal skin. Maintain skin warming for at least 15 minutes or until normal coloring and sensation have returned to the affected area. In case of massive exposure, remove clothing while showering with warm water. Seek medical evaluation and treatment as soon as possible.

First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an ophthalmologist immediately.. Get immediate medical attention.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (e.g, safety shower) is the preferred extinguishing media for clothing fires.

5.2. Special hazards arising from the substance or mixture

Fire Hazard : Oxidizing agent; vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion.

Reactivity : No reactivity hazard other than the effects described in sub-sections below.

5.3. Advice for firefighters

Firefighting instructions : DANGER! Extremely cold liquid and gas under pressure. Take care not to direct spray onto vents on top of container. Do not discharge sprays directly into liquid; cryogenic liquid can freeze water rapidly

Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA) and protective clothing. Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so. Onsite fire brigades must comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart L—Fire Protection.

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

Special protective equipment for : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fire fighters ^fighters.

Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat radiation may cause gas containers to rupture. Cool endangered containers with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems

Exposure to fire may cause containers to rupture/explode

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible.

If leaking do not spray water onto container. Water surrounding area (from protected position) to contain fire.

Other information : Do not walk on or roll equipment over a spill; any impact could cause an explosion. Smoking, flames, and electric sparks are potential explosion hazards in oxygen-enriched atmospheres

Containers are equipped with a pressure relief device. (Exceptions may exist where authorized by DOT.)

Cryogenic liquid causes severe frostbite, a burn-like injury. Heat of fire can build pressure in a closed container and cause it to rupture. Venting vapors may obscure visibility. Air will condense on surfaces such as vaporizers or piping exposed to liquid or cold gas. Nitrogen, which has a lower boiling point than oxygen, evaporates first, leaving an oxygenenriched condensate.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures :

Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. Ensure adequate air ventilation. Eliminate ignition sources. Evacuate area. Try to stop release. Monitor concentration of released product. Wear self-contained breathing apparatus when entering area unless atmosphere is proven to be safe. Stop leak if safe to do so.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Try to stop release.

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling :

Never use oxygen as a substitute for compressed air. Never use an oxygen jet for any type of cleaning, especially for cleaning clothing. Oxygen-saturated clothing may burst into flame at the slightest spark and be quickly consumed in an engulfing fire. Do not get liquid in eyes, on skin, or on clothing. Persons exposed to high concentrations of liquid oxygen should stay in a well-ventilated or open area for 30 minutes before entering a confined space or going near any source of ignition. Immediately remove clothing exposed to oxygen and air it out to reduce the likelihood of an engulfing fire. Prevent ignition sources, such as static electricity generated in clothing while walking

Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to open, discontinue use and contact your supplier. Close the container valve after each use; keep closed even when empty. Never apply flame or localized heat directly to any part of the container. High temperatures may damage the container and could cause the pressure relief device to fail prematurely, venting the container contents. For other precautions in using this product, see section 16.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions :

Store only where temperature will not exceed 125°F (52°C). Post “No Smoking/No Open Flames” signs in storage and use areas. There must be no sources of ignition. Separate packages and protect against potential fire and/or explosion damage following

appropriate codes and requirements (e.g, NFPA 30, NFPA 55, NFPA 70, and/or NFPA 221 in the U.S.) or according to requirements determined by the Authority Having Jurisdiction (AHJ). Always secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand when the container is not in use. Store full and empty containers separately. Use a first-in, first-out inventory system to prevent storing full containers for long periods. For other precautions in using this product, see section 16

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling

product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit

When working with cryogenic/cold liquid or gaseous oxygen under pressure, avoid using materials that are incompatible with oxygen use

When working with cryogenic/cold liquid or gas under pressure, avoid using materials that are incompatible with cryogenic use. Some metals, such as carbon steel, may fracture easily at low temperature. Use only transfer lines designed for cryogenic liquids. Prevent liquid or cold gas from being trapped in piping between valves. Equip the piping with pressure relief devices. Praxair recommends piping all vents to the exterior of the building.

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Oxygen, refrigerated liquid (7782-44-7)
ACGIH	Not established
USA OSHA	Not established

8.2. Exposure controls

Appropriate engineering controls : Avoid oxygen rich (>23.5%) atmospheres. Systems under pressure should be regularly checked for leakages. Ensure exposure is below occupational exposure limits (where available). Gas detectors should be used when oxidizing gases may be released. Oxygen detectors should be used when asphyxiating gases may be released. Provide adequate general and local exhaust ventilation. Consider work permit system e.g. for maintenance activities

Hand protection : Wear working gloves when handling gas containers.

Eye protection : Wear safety glasses with side shields. Wear goggles and a face shield when transfilling or breaking transfer connections.

Skin and body protection : Wear loose-fitting, cryogenic gloves, metatarsal shoes for container handling, and protective clothing where needed. Cuffless trousers should be worn outside the shoes. Gloves must be free of oil and grease. Select in accordance with OSHA 29 CFR 1910.132, 1910.136, and 1910.138.

Respiratory protection : None required under normal use. An air-supplied respirator must be used while working with this product in confined spaces. The respiratory protection used must conform with OSHA rules as specified in 29 CFR 1910.134. Select per OSHA 29 CFR 1910.134 and ANSI Z88.2.

Thermal hazard protection : Wear cold insulating gloves. Wear cold insulating gloves when transfilling or breaking transfer connections.

Environmental exposure controls : None necessary.

Other information : Consider the use of flame resistant safety clothing. Wear safety shoes while handling containers.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state :

Gas Appearance : Colorless gas.

Molecular mass : 32 g/mol

Color : Bluish liquid.

Odor : Odorless.

Odor threshold : No data available

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) : No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -219 °C (-362°F)

Freezing point : -218.4 °C (-361°F)

Boiling point : -183 °C (-297°F)

Flash point : No data available

Critical temperature : -118.6 °C (-181°F)

Auto-ignition temperature : Not applicable.

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : Not applicable.

Critical pressure : 50.4 bar (731.4 psia)

Relative vapor density at 20 °C : No data available

Relative density : 1.1

Density : 1.4289 kg/m?3; (at 21.1 °C)

Relative gas density : 1.1

Solubility :

Water : 39 mg/l

Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : Oxidizer.

Explosion limits : No data available

9.2. Other information

Gas group : Refrigerated liquefied gas

Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground level

SECTION 10: Stability and reactivity

10.1. Reactivity

No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

Risk of explosion if spilt on organic structural materials (e.g. wood or asphalt). Violently oxidizes organic material.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

Consult supplier for specific recommendations. Consider the potential toxicity hazard due to the presence of chlorinated or fluorinated polymers in high pressure (> 30 bar) oxygen lines in case of combustion. Keep equipment free from oil and grease. May react violently with combustible materials. May react violently with reducing agents.

10.6. Hazardous decomposition products

None

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified pH: Not applicable.

Serious eye damage/irritation : Not classified pH: Not applicable.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Oxygen, refrigerated liquid (7782-44-7)
Persistence and degradability	No ecological damage caused by this product.

12.3. Bioaccumulative potential

Oxygen, refrigerated liquid (7782-44-7)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

12.4. Mobility in soil

Oxygen, refrigerated liquid (7782-44-7)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.

12.5. Other adverse effects

Other adverse effects : Can cause frost damage to vegetation.

Effect on ozone layer : None

Effect on the global warming : No known effects from this product

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : Do not discharge into any place where its accumulation could be dangerous.

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1073 Oxygen, refrigerated liquid (cryogenic liquid), 2.2

UN-No.(DOT) : UN1073

Proper Shipping Name (DOT) : Oxygen, refrigerated liquid (cryogenic liquid)

Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115

Hazard labels (DOT) : 2.2 - Non-flammable gas

5.1 - Oxidizer

DOT Special Provisions (49 CFR 172.102) : T75 - When portable tank instruction T75 is referenced in Column (7) of the 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of 178.277 of this subchapter TP5 - For a portable tank used for the transport of flammable refrigerated liquefied gases or refrigerated liquefied oxygen, the maximum rate at which the portable tank may be filled must not exceed the liquid flow capacity of the primary pressure relief system rated at a pressure not exceeding 120 percent of the portable tank's design pressure. For portable tanks used for the transport of refrigerated liquefied helium and refrigerated liquefied atmospheric gas (except oxygen), the maximum rate at which the tank is filled must not exceed the liquid flow capacity of the pressure relief device rated at 130 percent of the portable tank's design pressure. Except for a portable tank containing refrigerated liquefied helium, a portable tank shall have an outage of at least two percent below the inlet of the pressure relief device or pressure control valve, under conditions of incipient opening, with the portable tank in a level attitude. No outage is required for helium TP22 - Lubricants for portable tank fittings (for example, gaskets, shut-off valves, flanges) must be oxygen compatible

Additional information

Emergency Response Guide (ERG) : 122 (UN1072)

Number

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Transport by sea

UN-No. (IMDG) : 1073

Proper Shipping Name (IMDG) : OXYGEN, REFRIGERATED LIQUID

Class (IMDG) : 2 - Gases

MFAG-No : 122

Air transport

UN-No. (IATA) : 1073

Proper Shipping Name (IATA) : Oxygen, refrigerated liquid

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations

Oxygen, refrigerated liquid (7782-44-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes	Sudden release of pressure hazard
	Immediate (acute) health hazard
	Fire hazard

All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

15.2. International regulations

CANADA

Oxygen, refrigerated liquid (7782-44-7)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Oxygen, refrigerated liquid (7782-44-7)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Oxygen, refrigerated liquid (7782-44-7)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Korean ECL (Existing Chemicals List) Substances)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical

15.2.2. National regulations

Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .
Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .
Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah Bahan Berbahaya dan Beracun.
SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards.

SBMA asks users of this product to study this SDS and become aware of the product hazards and safety information. To promote safe use of this product, a user should (1) notify employees, agents, and contractors of the information in this SDS and of any other known product hazards and safety information, (2) furnish this information to each purchaser of the product, and (3) ask each purchaser to notify its employees and customers of the product hazards and safety information

SBMA, it is the user's obligation to determine the conditions of safe use of the product The opinions expressed herein are those of qualified experts within SBMA. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and the conditions of use are not within the control of

SBMA, it is the user's obligation to determine the conditions of safe use of the product

SBMA SDSs are furnished on sale or delivery by SBMA or the independent distributors and suppliers who package and sell our products. To obtain current SDSs for these products, contact your SBMA sales representative, local distributor, or supplier. If you have questions regarding SBMA SDSs, would like the document number and date of the latest SDS, or would like the names of the SBMA suppliers in your area, phone or write the SBMA Call Center (Phone: 0542 - 743555; Address: SBMA Call Center, Jl Mulawarman KM 18 RT 24 No 70 Balikpapan - Kalimantan Timur, Indonesia)

NFPA health hazard : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

NFPA specific hazard : OX - This denotes an oxidizer, a chemical which can greatly increase the rate of combustion/fire.

HMIS III Rating

Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given

Flammability : 0 Minimal Hazard

Physical : 2 Moderate Hazard

OXYGEN

Purity > 99.6%
Pressure 150 BAR
Cylinder Vol. 40 L
Gas Vol. 6.3 M?3;
Valve BS341-3

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

MATERIAL SAFETY DATA SHEETS (MSDS)

Oxygen, compressed MSDS No. 112

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Oxygen, compressed

CAS No : 7782-44-7

Formula : O?

Other means of identification : Oxygen, Compressed; MediPure Oxygen; Aviator's Breathing Oxygen; USP Oxygen; Oxygen - Diving Grade

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Medical applications

Industrial use

Diving Gas (Underwater Breathing)

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp: (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification Ox. Gas 1	H270
Compressed gas 2.2. Label elements	H280
GHS-US labeling	:
Hazard pictograms (GHS-US)		GHS03 GHS04
Signal word (GHS-US)	:	DANGER
Hazard statements (GHS-US)	:	H270 - MAY CAUSE OR INTENSIFY FIRE; OXIDIZER H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
Precautionary statements (GHS-US)	:	P202 - Do not handle until all safety precautions have been read and understood P220 - Keep/Store away from combustible materials, clothing P244 - Keep reduction valves/valves and fittings free from oil and grease P271+P403 - Use and store only outdoors or in a well-ventilated place P370+P376 - In case of fire: Stop leak if safe to do so CGA-PG05 - Use a back flow preventive device in the piping CGA-PG20+CGA-PG10 - Use only with equipment of compatible materials of construction and rated for cylinder pressure CGA-PG22 - Use only with equipment cleaned for oxygen service CGA-PG21 - Open valve slowly CGA-PG06 - Close valve after each use and when empty CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3. Other hazards

Other hazards not contributing to : Breathing 80 percent or more oxygen at atmospheric pressure for more than a few hours _{the classification}may cause nasal stuffiness, cough, sore throat, chest pain, and breathing difficulty.

Breathing oxygen at higher pressure increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause lung damage and central nervous system (CNS) effects, resulting in dizziness, poor coordination, tingling sensation, visual and hearing disturbances, muscular twitching, unconsciousness, and convulsions. Breathing oxygen under pressure may cause prolongation of adaptation to darkness and reduced peripheral vision.

Oxygen, compressed MSDS No. 112

2.4. Unknown acute toxicity (GHS US)

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name	:	Oxygen, compressed
CAS No	:	7782-44-7
Name		Product identifier	%
Oxygen		(CAS No) 7782-44-7	99.5 - 100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Move to fresh air. Get medical advice/attention.

First-aid measures after skin contact : Adverse effects not expected from this product.

First-aid measures after eye contact : Adverse effects not expected from this product. In case of eye irritation: Rinse immediately with plenty of water. Consult an ophthalmologist if irritation persists.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (e.g, safety shower) is the preferred extinguishing media for clothing fires.

5.2. Special hazards arising from the substance or mixture

Fire Hazard : Oxidizing agent; vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion.

5.3. Advice for firefighters

Firefighting instructions : High-pressure, oxidizing gas

Special protective equipment for : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fire fighters ^fighters.

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible.

Other information : Heat of fire can build pressure in container and cause it to rupture. Containers are equipped with a pressure relief device. (Exceptions may exist where authorized by DOT.) No part of the container should be subjected to a temperature higher than 125°F (52°C). Smoking, flames, and electric sparks in the presence of enriched oxygen atmospheres are potential explosion hazards.

Oxygen, compressed MSDS No. 112

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Try to stop release.

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to open, discontinue use and contact your supplier. Close the container valve after each use; keep closed even when empty. Never apply flame or localized heat directly to any part of the container. High temperatures may damage the container and could cause the pressure relief device to fail prematurely, venting the container contents. For other precautions in using this product, see section 16.

Safe use of the product : The suitability of this product as a component in underwater breathing gas mixtures is to be determined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the physiological effects, methods employed, frequency and duration of use, hazards, side effects, and precautions to be taken.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store only where temperature will not exceed 125°F (52°C). Post “No Smoking/No Open Flames” signs in storage and use areas. There must be no sources of ignition. Separate packages and protect against potential fire and/or explosion damage following appropriate codes and requirements (e.g, NFPA 30, NFPA 55, NFPA 70, and/or NFPA 221 in the U.S.) or according to requirements determined by the Authority Having Jurisdiction (AHJ). Always secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand when the container is not in use. Store full and empty containers separately. Use a first-in, first-out inventory system to prevent storing full containers for long periods. For other precautions in using this product, see section 16

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

Oxygen, compressed MSDS No. 112

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Oxygen, compressed (7782-44-7)
ACGIH	Not established
USA OSHA	Not established
Oxygen, compressed (7782-44-7)
ACGIH	Not established
USA OSHA	Not established

8.2. Exposure controls

Appropriate engineering controls : Avoid oxygen rich (>23.5%) atmospheres. Use a local exhaust system with sufficient flow velocity to maintain an adequate supply of air in the worker's breathing zone. Mechanical (general): General exhaust ventilation may be acceptable if it can maintain an adequate supply of air.(minimum of 19.5 percent) and a safe carbon dioxide level.

Eye protection : Wear safety glasses with side

Skin and body protection : Wear metatarsal shoes and work gloves for cylinder handling, and protective clothing where needed. Wear appropriate chemical gloves during cylinder changeout or wherever contact with product is possible. Select per OSHA 29 CFR 1910.132, 1910.136, and 1910.138. As needed for welding, wear hand, head, and body protection to help prevent injury from radiation and sparks. (See ANSI Z49.1.) At a minimum, this includes welder’s gloves and protective goggles, and may include arm protectors, aprons, hats, and shoulder protection as well as substantial clothing.

Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable). Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the respirator has the appropriate protection factor for the exposure level. If cartridge type respirators are used, the cartridge must be appropriate for the chemical exposure. For emergencies or instances with unknown exposure levels, use a self-contained breathing apparatus (SCBA).

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 32 g/mol

Color : Colorless.

Odor : No odor warning properties.

Odor threshold : No data available

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -219 °C (-362°F)

Freezing point : No data available

Boiling point : -183 °C (-297°F)

Flash point : Not applicable.

Critical temperature : -118.6 °C (-181.48°F)

Auto-ignition temperature : Not applicable.

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : Not applicable.

Critical pressure : 50.4 bar (731.4 psia)

Oxygen, compressed MSDS No. 112

Relative vapor density at 20 °C : 0.0827 lb/ft3 (1.325 kg/m3) absolute vapor density at 70°F/21.1°C, 1 atm

Relative density : 1.1

Density : 1.4289 kg/m?3; (at 21.1 °C)

Relative gas density : 1.1

Solubility :

Water: 39 mg/l

Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : Oxidizer.

Explosion limits : No data available

9.2. Other information

Gas group : Compressed gas

Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground level

SECTION 10: Stability and reactivity

10.1. Reactivity

No additional information available

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

Violently oxidizes organic material.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

Keep equipment free from oil and grease. Consider the potential toxicity hazard due to the presence of chlorinated or fluorinated polymers in high pressure (> 30 bar) oxygen lines in case of combustion. May react violently with combustible materials. May react violently with reducing agents.

10.6. Hazardous decomposition products

None

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified pH: Not applicable.

Serious eye damage/irritation : Not classified pH: Not applicable.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Oxygen, compressed (7782-44-7)
Persistence and degradability	No ecological damage caused by this product.
Oxygen, compressed (7782-44-7)
Persistence and degradability	No ecological damage caused by this product.

Oxygen, compressed MSDS No. 112

12.3. Bioaccumulative potential

Oxygen, compressed (7782-44-7)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.
Oxygen, compressed (7782-44-7)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

12.4. Mobility in soil

Oxygen, compressed (7782-44-7)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.
Oxygen, compressed (7782-44-7)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.

12.5. Other adverse effects

Effect on ozone layer : None

Effect on the global warming : No known effects from this product

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1072 Oxygen, compressed, 2.2

UN-No.(DOT) : UN1072

Proper Shipping Name (DOT) : Oxygen, compressed

Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115

Hazard labels (DOT) : 2.2 - Non-flammable gas

5.1 - Oxidizer

DOT Special Provisions : 110 - Fire extinguishers transported under UN1044 may include installed actuating (49 CFR 172.102) cartridges (cartridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the aggregate quantity of deflagrating (propellant) explosives does not exceed 3.2 grams per extinguishing unit A14 - This material is not authorized to be transported as a limited quantity or consumer commodity in accordance with 173.306 of this subchapter when transported aboard an aircraft

Oxygen, compressed MSDS No. 112

Additional information

Emergency Response Guide (ERG)

Number : 122 (UN1072)

Other information : No supplementary information available.

Transport by sea

UN-No. (IMDG) : 1072

Proper Shipping Name (IMDG) : OXYGEN, COMPRESSED

Class (IMDG) : 2 - Gases

MFAG-No : 122

Air transport

UN-No. (IATA) : 1072

Proper Shipping Name (IATA) : Oxygen, compressed

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure

15.1. US Federal regulations

Oxygen, compressed (7782-44-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes	Sudden release of pressure hazard
	Fire hazard

All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

15.2. International regulations

CANADA

Oxygen, compressed (7782-44-7)

Listed on the Canadian DSL (Domestic Substances List)

Oxygen, compressed (7782-44-7)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Oxygen, compressed (7782-44-7)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Oxygen, compressed (7782-44-7)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Korean ECL (Existing Chemicals List) Substances)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical

Oxygen, compressed MSDS No. 112

15.2.2. National regulations

- Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .

- Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .

- Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.

- SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards.

Obtain and evaluate the safety information for each component before you produce the mixture. Consult an industrial hygienist or other trained person when you evaluate the end product. Before using any plastics, confirm their compatibility with this product SBMA asks users of this product to study this SDS and become aware of the product hazards and safety information. To promote safe use of this product, a user should (1) notify employees, agents, and contractors of the information in this SDS and of any other known product hazards and safety information, (2) furnish this information to each purchaser of the product, and (3) ask each purchaser to notify its employees and customers of the product hazards and safety information

The opinions expressed herein are those of qualified experts within SBMA. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and the conditions of use are not within the control of SBMA, it is the user's obligation to determine the conditions of safe use of the product The opinions expressed herein are those of qualified experts within SBMA. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and the conditions of use are not within the control of SBMA, it is the user's obligation to determine the conditions of safe use of the product SBMA SDSs are furnished on sale or delivery by SBMA or the independent distributors and suppliers who package and sell our products. To obtain current SDSs for these products, contact your SBMA sales representative, local distributor, or supplier. If you have questions regarding SBMA SDSs, would like the document number and date of the latest SDS, or would like the names of the SBMA suppliers in your area, phone or write the SBMA Call Center (Phone: 0542 - 743555; Address: SBMA Call Center, Jl Mulawarman KM 18 RT 24 No 70 Balikpapan - Kalimantan Timur, Indonesia)

NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard

beyond that of ordinary combustible materials.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water.

NFPA specific hazard : OX - This denotes an oxidizer, a chemical which can greatly increase the rate of combustion/fire.

HMIS III Rating

Health 0 Minimal Hazard - No significant risk to health

Flammability 0 Minimal Hazard Physical

3 Serious Hazard

ACETYLENE

Purity > 98%
FP 15.5 BAR
Mass 5 Kg
Cylinder Vol 40 L
Valve BS341-4

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

MATERIAL SAFETY DATA SHEETS (MSDS)

Acetylene, dissolved MSDS No. 101

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Acetylene, dissolved

CAS No : 74-86-2

Formula : C2H2

Other means of identification : Acetylene, ethine, ethyne, narcylene

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use. Use as directed.

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification

Flam. Gas 1 H220

GHS02 GHS04

Signal word (GHS-US) : DANGER

Hazard statements (GHS-US) : H220 - EXTREMELY FLAMMABLE GAS

H231 - MAY REACT EXPLOSIVELY EVEN IN THE ABSENCE OF AIR AT ELEVATED

PRESSURE AND/OR TEMPERATURE

H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED

OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION

CGA-HG04 - MAY FORM EXPLOSIVE MIXTURES WITH AIR

Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from Heat, Open flames, Sparks, Hot surfaces. - No smoking P271+P403 - Use and store only outdoors or in a well-ventilated place

P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely

P381 - Eliminate all ignition sources if safe to do so

P501 - Dispose of contents/container in accordance with container Supplier

/owner instructions

CGA-PG05 - Use a back flow preventive device in the piping

CGA-PG13 - Fusible plugs in the top, bottom, or valve melt at 98 °C to 107 °C

(208 °F to 224°F). Do not discharge at pressures above 15 psig (103 kPa)

CGA-PG06 - Close valve after each use and when empty

CGA-PG11 - Never put cylinders into unventilated areas of passenger vehicles

CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

Acetylene, dissolved MSDS No. 101

2.3. Other hazards

Other hazards not contributing to the classification

For safety reasons, the acetylene is dissolved in acetone (CAS # 67-64-1; Flam. Liq. 2, Eye Irrit. 2, STOT SE 3) in the gas container. Vapor of the solvent is carried away as impurity when the acetylene is extracted from the gas container. The concentration of the solvent vapor in the gas is lower than the concentration limits to change the classification of the acetylene.

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name	Product identifier	%
Acetylene, dissolved (Main constituent)	(CAS No) 74-86-2	100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.

First-aid measures after skin contact : The liquid may cause frostbite. For exposure to liquid, immediately warm frostbite area with

warm water not to exceed 105°F (41°C). Water temperature should be tolerable to normal skin. Maintain skin warming for at least 15 minutes or until normal coloring and sensation have returned to the affected area. In case of massive exposure, remove clothing while showering with warm water. Seek medical evaluation and treatment as soon as possible.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

Obtain medical assistance.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : See below. See CGA Pamphlet SB-4, Handling Acetylene Cylinders in Fire Situations, for further information.

5.2. Special hazards arising from the substance or mixture

Fire Hazard : EXTREMELY FLAMMABLE GAS. If venting or leaking gas catches fire, do not extinguish flames. Flammable vapors may spread from leak, creating an explosive reignition hazard. Vapors can be ignited by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static discharge, or other ignition sources at locations distant from product handling point. Explosive atmospheres may linger. Before entering an area, especially a confined area, check the atmosphere with an appropriate device.

Explosion Hazard : EXTREMELY FLAMMABLE GAS. Forms explosive mixtures with air and oxidizing agents.

Reactivity : No reactivity hazard other than the effects described in sub-sections below.

5.3. Advice for firefighters

Firefighting instructions : Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA) and protective clothing. Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart L—Fire Protection.

Acetylene, dissolved MSDS No. 101

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.

Special protective equipment for : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fire fighters fighters.

Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat radiation may cause gas containers to rupture. Cool endangered containers with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible

Continue water spray from protected position until container stays cool.

Other information : Acetylene containers are provided with pressure relief devices designed to vent contents when exposed to elevated temperature.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Wear self-contained breathing apparatus when entering area unless atmosphere is proven to be safe. Evacuate area. Ensure adequate ventilation. Stop leak if safe to do so.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution. Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only non-sparking tools. Use only explosion-proof equipment.

7.2. Conditions for safe storage, including any incompatibilities

Acetylene, dissolved MSDS No. 101

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

Storage area : Acetylene trailers are designed and intended for outdoor use. Acetylene storage in excess of 2.500 cu ft (70.79 cubic meters) is prohibited in buildings and other occupancies.

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Acetylene, dissolved (74-86-2)
ACGIH	Not established
USA OSHA	Not established

8.2. Exposure controls

Appropriate engineering controls : An explosion-proof local exhaust system or a mechanical system is acceptable if it can prevent oxygen deficiency and keep hazardous fumes and gases below all applicable exposure limits in the worker's breathing area. During welding, ensure that there is adequate ventilation to keep worker exposure below applicable limits for fumes, gases, and other byproducts of welding. Do not breathe fumes or gases. Short-term overexposure to fumes may cause dizziness, nausea, and dryness or irritation of the nose, throat, and eyes, or may cause other similar discomfort.

Eye protection : Wear safety glasses with side shields.

Skin and body protection : As needed for welding, wear hand, head, and body protection to help prevent injury from radiation and sparks. (See ANSI Z49.1.) At a minimum, this includes welder’s gloves and protective goggles, and may include arm protectors, aprons, hats, and shoulder protection as well as substantial clothing.

Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.

Environmental exposure controls : Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment.

Other information : Consider the use of flame resistant anti-static safety clothing. Wear leather safety gloves and safety shoes when handling cylinders.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 26 g/mol

Color : Colorless.

Odor : Garlic like. Poor warning properties at low concentrations.

Odor threshold : No data

available pH : Not applicable.

Relative evaporation rate (butyl acetate=1) : No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -80.8 °C (-113.4°F)

Freezing point : No data available

Acetylene, dissolved MSDS No. 101

Boiling point : -84 °C (-119.2°F)

Flash point : -17 °C (1.4°F)

Critical temperature : 36 °C (97°F)

Auto-ignition temperature : 305 °C (581°F)

Decomposition temperature : 635 °C (1175°F)

Flammability (solid, gas) : 2.5 - 100 vol %

Vapor pressure : 44 bar (623 psig)

Critical pressure : 61.38 bar (875 psig)

Relative vapor density at 20 °C : No data available

Relative density : Not applicable.

Density : 0.0012 g/cm?3; (at 0 °C)

Relative gas density : 0.9

Solubility : Water: 1185 mg/l

Log Pow : 0.37

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None.

Explosion limits : No data available

9.2. Other information

Sublimation point : -83.3 °C

Gas group : Dissolved gas

SECTION 10: Stability and reactivity

10.1. Reactivity

No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability

Dissolved in a solvent supported in a porous mass. Stable under recommended handling and storage conditions (see section 7).

10.3. Possibility of hazardous reactions

May react explosively even in the absence of air. May decompose violently at high temperature and/or pressure or in the presence of a catalyst. Can form explosive mixture with air. May react violently with oxidants.

10.4. Conditions to avoid

High temperature. High pressure. Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

10.5. Incompatible materials

Forms explosive acetylides with copper, silver and mercury. Do not use alloys containing more than 65% copper. Air, Oxidizer. Do not use alloys containing more than 43% silver.

10.6. Hazardous decomposition products

Thermal decomposition or burning may produce carbon monoxide, carbon dioxide, and hydrogen. The welding and cutting process may form reaction products such as carbon monoxide and carbon dioxide. Other decomposition products of normal operation originate from the volatilization, reaction, or oxidation of the material being worked.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified pH: Not Applicable

Serious eye damage/irritation : Not classified pH: Not Applicable

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

Acetylene, dissolved MSDS No. 101

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general		:	No known ecological damage caused by this product.
12.2. Persistence and degradability
Acetylene, dissolved (74-86-2)
Persistence and degradability			Will rapidly degrade by indirect photolysis in air. Will not undergo hydrolysis.
12.3. Bioaccumulative potential
	Acetylene, dissolved (74-86-2)
	Log Pow			0.37
	Log Kow			Not applicable.
	Bioaccumulative potential			Not expected to bioaccumulate due to the low log Kow (log Kow < 4>

12.4. Mobility in soil

Acetylene, dissolved (74-86-2)
Mobility in soil	No data available.
Ecology - soil	Because of its high volatility, the product is unlikely to cause ground or water pollution.

12.5. Other adverse effects

Effect on ozone layer : No known effects from this product

Effect on the global warming : No known effects from this product

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1001 Acetylene, dissolved, 2.1

UN-No.(DOT) : UN1001

Proper Shipping Name (DOT) : Acetylene, dissolved

Hazard labels (DOT) : 2.1 - Flammable gas

DOT Special Provisions : N86 - UN pressure receptacles made of aluminum alloy are not authorized N88 - Any metal (49 CFR 172.102) part of a UN pressure receptacle in contact with the contents may not contain more than 65% copper, with a tolerance of 1%

Additional information

Emergency Response Guide (ERG)

Number : 116 (UN1001)

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's: compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or:plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Acetylene, dissolved MSDS No. 101

Transport by sea

UN-No. (IMDG) : 1001

Proper Shipping Name (IMDG) : Acetylene, dissolved

Class (IMDG) : 2 - Gases

MFAG-No : 116

Air transport

UN-No. (IATA) : 1001

Proper Shipping Name (IATA) : Acetylene, dissolved

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases flammable under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations

Acetylene, dissolved (74-86-2)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

SARA Section 311/312 Hazard Classes

Sudden release of pressure hazard

Reactive hazard

Fire hazard

All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

15.2. International regulations

CANADA

Acetylene, dissolved (74-86-2)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Acetylene, dissolved (74-86-2)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Acetylene, dissolved (74-86-2)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory

Listed on the Korean ECL (Existing Chemicals List)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)

Listed on the Canadian IDL (Ingredient Disclosure List)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

Listed on CICR (Turkish Inventory and Control of Chemicals)

15.2.2. National regulations

- Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .

- Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .

- Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.

- SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

15.3. US State regulations

Acetylene, dissolved (74-86-2)
U.S. - California - Proposition 65 - Carcinogens List	No
U.S. - California - Proposition 65 - Developmental Toxicity	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Female	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Male	No
State or local regulations	U.S - Massachusetts - Right To Know List U.S - New Jersey-Right to Know Hazard Substance List U.S - Pennsylvania - RTK (Right to Know) List

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

Acetylene, dissolved MSDS No. 101

SECTION 16: Other information

Other information : When using this product in welding and cutting, read and understand the manufacturer’s instructions and the precautionary label on the product. Ask your welding products supplier for a copy of SBMA’s free safety booklet, P-2035, Precautions and Safe Practices for Gas Welding, Cutting, and Heating, and for other manufacturers’ safety publications. For a detailed treatment, get ANSI Z49.1, Safety in Welding, Cutting, and Allied Processes, published by the American Welding Society (AWS), www.aws.org. Order AWS documents from Global Engineering Documents, global.ihs.com. Arcs and sparks can ignite combustible materials. Prevent fires. Refer to NFPA 51B, Standard for Fire Prevention During Welding, Cutting, and Other Hotwork. Do not strike an arc on the container. The defect produced by an arc burn may lead to container rupture.

When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an industrial hygienist or other trained person when you evaluate the end product. Before using any plastics, confirm their compatibility with this product.

NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard

beyond that of ordinary combustible materials.

NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure

and temperature, or is readily dispersed in air and will burn readily.

NFPA reactivity : 2 - Normally unstable and readily undergo violent

decomposition but do not detonate. Also: may react violently with water or may form potentially explosive mixtures with water. HMIS III Rating

Health 2 Moderate Hazard - Temporary or minor injury may occur

Flammability 4 Severe Hazard

Physical 2 Moderate Hazard

ARGON HP

Purity 99.99%
Pressure 150 BAR
H?2;O < 5> CnHm < 3> Vol 6.3 M?3;
Valve BS341-3

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

INDUSTRI GAS ACETYLENE - OXYGEN - NITROGEN - ARGON - DLL

MATERIAL SAFETY DATA SHEETS (MSDS)

Argon MSDS No. 103

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Argon

CAS No : 7440-37-1

Formula : Ar

Other means of identification : Shielding gas, argon 40

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use. Use as directed.

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification H280

Compressed gas

2.2 Label elements

GHS-US labeling	:
Hazard pictograms (GHS-US)		GHS04
Signal word (GHS-US)	:	WARNING
Hazard statements (GHS-US)	:	H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
Precautionary statements (GHS-US)	:	P202 - Do not handle until all safety precautions have been read and understood P271+P403 - Use and store only outdoors or in a well-ventilated place CGA-PG05 - Use a back flow preventive device in the piping CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG06 - Close valve after each use and when empty CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3 Other hazards

Other hazards not contributing to : Asphyxiant in high the classification

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name	:	Argon
CAS No	:	7440-37-1
Name		Product identifier	%
Argon		(CAS No) 7440-37-1	99.5 - 100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after skin contact : Adverse effects not expected from this product.

First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open

and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an ophthalmologist immediately.. Get immediate medical attention.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixture

Reactivity : No reactivity hazard other than the effects described in sub-sections below.

5.3. Advice for firefighters

Firefighting instructions : Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA) and protective clothing. Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart L—Fire Protection.

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.

Special protective equipment for : Use self-contained breathing apparatus. Standard protective clothing and equipment (Self _{fire fighters}Contained Breathing Apparatus) for fire fighters.

Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat

radiation may cause gas containers to rupture. Cool endangered containers with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures

Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. Evacuate area. Ensure adequate air ventilation. Wear self-contained breathing apparatus when entering area unless atmosphere is proven to be safe. Stop leak if safe to do so.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Try to stop release.

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in a cool, well-ventilated place. Store and use with adequate ventilation. Store only where temperature will not exceed 125°F (52°C). Firmly secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand. Store full and empty containers separately. Use a first-in, first-out inventory system to prevent storing full containers for long periods

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Argon (7440-37-1)
ACGIH	Not established
USA OSHA	Not established
Argon (7440-37-1)
ACGIH	Not established
USA OSHA	Not established

8.2. Exposure controls

Appropriate engineering controls : Oxygen detectors should be used when asphyxiating gases may be released. Systems under pressure should be regularly checked for leakages. Provide adequate general and local exhaust ventilation. Consider work permit system e.g. for maintenance activities.

Hand protection : Wear working gloves when handling gas containers.

Eye protection : Wear safety glasses with side shields.

Thermal hazard protection : None necessary.

Environmental exposure controls : None necessary.

Other information : Wear safety shoes while handling containers.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 40 g/mol

Color : Colorless.

Odor : No odor warning properties.

Odor threshold : No data

available pH : Not applicable.

Relative evaporation rate (butyl acetate=1) : No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -189 °C

Freezing point : No data available

Boiling point : -185.9 °C

Flash point : No data available

Critical temperature : -122.4 °C

Auto-ignition temperature : Not applicable.

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : Not applicable.

Critical pressure : 4898 kPa

Argon MSDS No. 103

Relative vapor density at 20 °C : No data available

Relative density : No data available

Density : 0.103 lb/ft3 Vapor density at 70°F (21.1°C)

Relative gas density : 1.38

Solubility :

Water: 61 mg/l Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None.

Explosion limits : No data available

9.2. Other information

Gas group : Compressed gas

Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground level

SECTION 10: Stability and reactivity

10.1. Reactivity

No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

None

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

Using this product in welding and cutting may create additional hazards. The arc from electric arc welding may form gaseous reaction products such as carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. Other decomposition products of arc welding and cutting originate from the volatilization, reaction, and oxidization of the material being worked.

10.6. Hazardous decomposition products

None

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

pH : Not applicable.

Serious eye damage/irritation : Not classified

pH : Not applicable.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Argon (7440-37-1)
Persistence and degradability	No ecological damage caused by this product.
Argon (7440-37-1)
Persistence and degradability	No ecological damage caused by this product.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : May be vented to atmosphere in a well ventilated place. Consult supplier for specificrecommendations. Do not discharge into any place where its accumulation could be dangerous. Contact supplier if guidance is required.

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1006 Argon, compressed, 2.2

UN-No.(DOT) : UN1006

Proper Shipping Name (DOT) : Argon, compressed

Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115

Hazard labels (DOT) : 2.2 non-flammable gas

Additional information

Emergency Response Guide (ERG)

number : 121 UN(1006);120 UN(1951)

Other information : No supplementary information available.

Transport by sea

UN-No. (IMDG) : 1006

Proper Shipping Name (IMDG) : ARGON, COMPRESSED

Class (IMDG) : 2 - Gases

MFAG-No : 121

Air transport

UN-No. (IATA) : 1006

Proper Shipping Name (IATA) : Argon, compressed

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases non-flammable nontoxic under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations

Argon (7440-37-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes	Sudden release of pressure hazard

All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

15.2. International regulations

CANADA

Argon (7440-37-1)

Listed on the Canadian DSL (Domestic Substances List)

Argon (7440-37-1)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Argon (7440-37-1)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Argon (7440-37-1)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Korean ECL (Existing Chemicals List) Substances)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical

15.2.2. National regulations

Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .
Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .
Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.
SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

15.3. US State regulations

Argon (7440-37-1)
U.S. - California - Proposition 65 - Carcinogens List	No
U.S. - California - Proposition 65 - Developmental Toxicity	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Female	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Male	No
State or local regulations	U.S - Massachusetts - Right To Know List U.S - New Jersey-Right to Know Hazard Substance List U.S - Pennsylvania - RTK (Right to Know) List

SECTION 16 : Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards.

PRESENCE OF CHLORINATED HYDROCARBON VAPORS—HIGHLY TOXIC

PHOSGENE MAY BE PRODUCED. Metal coatings such as paint, plating, or galvanizing may generate harmful fumes when heated. Residues from cleaning materials may also be harmful. AVOID ARC OPERATIONS ON PARTS WITH PHOSPHATE RESIDUES (ANTIRUST, CLEANING PREPARATIONS)—HIGHLY TOXIC PHOSPHINE MAY BE PRODUCED

NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

NFPA specific hazard : SA - This denotes gases which are simple asphyxiants.

HMIS III Rating

Health 0 Minimal Hazard - No significant risk to health

Flammability 0 Minimal Hazard

Physical 3 Serious Hazard

ARGON UHP

Purity 99.9995 %
Pressure 200 BAR
H?2;O < 2> O?2; < 3> CnHm < 1> Vol 10.5 M?3;
Valve BS341-3

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

INDUSTRI GAS ACETYLENE - OXYGEN - NITROGEN - ARGON - DLL

MATERIAL SAFETY DATA SHEETS (MSDS)

Argon UHP MSDS No. 116

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Argon UHP

CAS No : 7440-37-1

Formula : Ar

Other means of identification : Shielding gas, argon 40

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use. Use as directed.

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp: (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification H280

compressed gas

2.2. Label elements

GHS-US labeling	:
Hazard pictograms (GHS-US)		GHS04
Signal word (GHS-US)	:	WARNING
Hazard statements (GHS-US)	:	H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
Precautionary statements (GHS-US)	:	P202 - Do not handle until all safety precautions have been read and understood P271+P403 - Use and store only outdoors or in a well-ventilated place CGA-PG05 - Use a back flow preventive device in the piping CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG06 - Close valve after each use and when empty CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3. Other hazards

Other hazards not contributing to : Asphyxiant in high the classification

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name	:	Argon
CAS No	:	7440-37-1
Name		Product identifier	%
Argon		(CAS No) 7440-37-1	99.5 - 100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after skin contact : Adverse effects not expected from this product.

First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open

and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an ophthalmologist immediately.. Get immediate medical attention.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixture

Reactivity : No reactivity hazard other than the effects described in sub-sections below

5.3. Advice for firefighters

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.

Special protective equipment for : Use self-contained breathing apparatus. Standard protective clothing and equipment (Self _{fire fighters}Contained Breathing Apparatus) for fire fighters.

Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Try to stop release.

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from physical

damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to open, discontinue use and contact your supplier. Close the container valve after each use; keep closed even when empty. Never apply flame or localized heat directly to any part of the container. High temperatures may damage the container and could cause the pressure relief device to fail prematurely, venting the container contents. For other precautions in using this product, see section 16.

7.2. Conditions for safe storage, including any incompatibilities

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Argon (7440-37-1)
ACGIH	Not established
USA OSHA	Not established
Argon (7440-37-1)
ACGIH	Not established
USA OSHA	Not established

8.2. Exposure controls

Appropriate engineering controls : Oxygen detectors should be used when asphyxiating gases may be released. Systems

under pressure should be regularly checked for leakages. Provide adequate general and local exhaust ventilation. Consider work permit system e.g. for maintenance activities.

Hand protection : Wear working gloves when handling gas containers.

Eye protection : Wear safety glasses with side shields.

Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program

that meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable). Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the respirator has the appropriate protection factor for the exposure level. If cartridge type respirators are used, the cartridge must be appropriate for the chemical exposure. For emergencies or instances with unknown exposure levels, use a self-contained breathing apparatus (SCBA).

Thermal hazard protection : None necessary.

Environmental exposure controls : None necessary.

Other information : Wear safety shoes while handling containers.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 40 g/mol

Color : Colorless.

Odor : No odor warning properties.

Odor threshold : No data available

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -189 °C

Freezing point : No data available

Boiling point : -185.9 °C

Flash point : No data available

Critical temperature : -122.4 °C

Auto-ignition temperature : Not applicable.

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : Not applicable.

Critical pressure : 4898 kPa

Relative vapor density at 20 °C : No data available

Relative density : No data available

Density : 0.103 lb/ft3 Vapor density at 70°F (21.1°C)

Relative gas density : 1.38

Solubility :

Water : 61 mg/l

Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None.

Explosion limits : No data available

9.2. Other information

Gas group : Compressed gas

Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below

ground level

SECTION 10: Stability and reactivity

10.1. Reactivity

No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

None.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

10.6. Hazardous decomposition products

None

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

pH: Not applicable.

Serious eye damage/irritation : Not classified

pH: Not applicable.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Argon (7440-37-1)
Persistence and degradability	No ecological damage caused by this product.
Argon (7440-37-1)
Persistence and degradability	No ecological damage caused by this product.

12.3. Bioaccumulative potential

Argon (7440-37-1)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.
Argon (7440-37-1)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

12.4. Mobility in soil

Argon (7440-37-1)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.
Argon (7440-37-1)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.

12.5. Other adverse effects

Effect on ozone layer : None

Effect on the global warming : None

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods May be vented to atmosphere in a well ventilated place. Consult supplier for specific

recommendations. Do not discharge into any place where its accumulation could be dangerous. Contact supplier if guidance is required.

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1006 Argon, compressed, 2.2

UN-No.(DOT) : UN1006

Proper Shipping Name (DOT) : Argon, compressed

Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115

Hazards label (DOT) : 2.2 - non-flammable gas

Additional information

Emergency Response Guide (ERG)

Number : 121 (UN1006);120 (UN1951)

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's

compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Transport by sea

UN-No. (IMDG) : 1006

Proper Shipping Name (IMDG) : ARGON, COMPRESSED

Class (IMDG) : 2 - Gases

MFAG-No : 121

Air transport

UN-No. (IATA) : 1006

Proper Shipping Name (IATA) : Argon, compressed

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations

Argon (7440-37-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes	Sudden release of pressure hazard

All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

CANADA

Argon (7440-37-1)

Listed on the Canadian DSL (Domestic Substances List)

Argon (7440-37-1)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Argon (7440-37-1)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Argon (7440-37-1)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Korean ECL (Existing Chemicals List) Substances)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical

15.2.2. National regulations

Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .
Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .
Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.
SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

15.3. US State regulations

Argon (7440-37-1)
U.S. - California - Proposition 65 - Carcinogens List	No
U.S. - California - Proposition 65 - Developmental Toxicity	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Female	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Male	No
State or local regulations	U.S - Massachusetts - Right To Know List U.S - New Jersey-Right to Know Hazard Substance List U.S - Pennsylvania - RTK (Right to Know) List

SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards.

PRESENCE OF CHLORINATED HYDROCARBON VAPORS—HIGHLY TOXIC

Center (Phone: 0542 - 743555; Address: SBMA Call Center, Jl Mulawarman KM 18 RT 24 No 70 Balikpapan - Kalimantan Timur, Indonesia)

NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard

beyond that of ordinary combustible materials.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water.

NFPA specific hazard : SA - This denotes gases which are simple asphyxiants.

HMIS III Rating

Health 0 Minimal Hazard - No significant risk to health

Flammability 0 Minimal Hazard

Physical 3 Serious Hazard

He UHP

Purity 99.995 %
Pressure 200 BAR
H?2;O < 3> O?2; < 3> CnHm < 1> Vol 9.1 M?3;
Valve BS 341-3

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

INDUSTRI GAS ACETYLENE - OXYGEN - NITROGEN - ARGON - DLL

Helium, compressed MSDS No. 106

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Helium, compressed

CAS No : 7440-59-7

Formula : He

Other means of identification : Helium-4, refrigerant gas R-704, LaserStar Helium, Medipure Helium, UltraLift Helium, Helium - Diving Grade

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use

Medical applications

Diving Gas (Underwater Breathing)

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification Compressed gas

H280

2.2. Label elements

GHS-US labeling	:	GHS04
Hazard pictograms (GHS-US)
Signal word (GHS-US)	:	WARNING
Hazard statements (GHS-US)	:	H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
Precautionary statements (GHS-US)	:	P202 - Do not handle until all safety precautions have been read and understood P271 - Use and store only outdoors or in a well-ventilated area P403 - Use and store only outdoors or in a well-ventilated place CGA-PG05 - Use a back flow preventive device in the piping CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG06 - Close valve after each use and when empty CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3. Other hazards

Other hazards not contributing to : Asphyxiant in high concentrations.

the classification

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name : Helium, compressed

CAS No : 7440-59-7

Name	Product identifier	%
Helium	(CAS No) 7440-59-7	99.5 - 100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation :

Remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. If breathing is difficult, trained personnel should give oxygen. Call a physician.

First-aid measures after skin contact : Adverse effects not expected from this product.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.

Special protective equipment for : Use self-contained breathing apparatus. Standard protective clothing and equipment (Self _{fire fighters}Contained Breathing Apparatus) for fire fighters.

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures

Evacuate area. Ensure adequate air ventilation. Wear self-contained breathing apparatus when entering area unless atmosphere is proven to be safe. Stop leak if safe to do so.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Try to stop release

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

PURIFIER ACETYLENE

Purity > 99.6%
FP 15.5 BAR
Mass 6 Kg
Cylinder Vol 40 L
Valve BS341-4

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

MATERIAL SAFETY DATA SHEETS(MSDS)

Acetylene, dissolved MSDS No. 101

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Acetylene, dissolved

CAS No : 74-86-2

Formula : C?H?

Other means of identification : Acetylen, ethine, ethyne, narcylene

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use. Use as directed.

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification

Flam. Gas 1 H220

GHS02 GHS04

Signal word (GHS-US) : DANGER

Hazard statements (GHS-US) : H220 - EXTREMELY FLAMMABLE GAS

H231 - MAY REACT EXPLOSIVELY EVEN IN THE ABSENCE OF AIR AT ELEVATED

PRESSURE AND/OR TEMPERATURE

H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED

OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION

CGA-HG04 - MAY FORM EXPLOSIVE MIXTURES WITH AIR

P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely

P381 - Eliminate all ignition sources if safe to do so

P501 - Dispose of contents/container in accordance with container Supplier

/owner instructions

CGA-PG05 - Use a back flow preventive device in the piping

CGA-PG13 - Fusible plugs in the top, bottom, or valve melt at 98 °C to 107 °C

(208 °F to 224°F). Do not discharge at pressures above 15 psig (103 kPa)

CGA-PG06 - Close valve after each use and when empty

CGA-PG11 - Never put cylinders into unventilated areas of passenger vehicles

CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

Acetylene, dissolved MSDS No. 101

2.3. Other hazards

Other hazards not contributing to the classification

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name

Product identifier

Acetylene, dissolved

(Main constituent)

(CAS No) 74-86-2

100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

Obtain medical assistance.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : See below. See CGA Pamphlet SB-4, Handling Acetylene Cylinders in Fire Situations, for further information.

5.2. Special hazards arising from the substance or mixture

Explosion Hazard : EXTREMELY FLAMMABLE GAS. Forms explosive mixtures with air and oxidizing agents.

Reactivity : No reactivity hazard other than the effects described in sub-sections below.

5.3. Advice for firefighters

Acetylene, dissolved MSDS No. 101

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.

Special protective equipment for : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fire fighters fighters.

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible

Continue water spray from protected position until container stays cool.

Other information : Acetylene containers are provided with pressure relief devices designed to vent contents when exposed to elevated temperature.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures :Wear self-contained breathing apparatus when entering area unless atmosphere is proven to be safe. Evacuate area. Ensure adequate ventilation. Stop leak if safe to do so.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only non-sparking tools. Use only explosion-proof equipment

7.2. Conditions for safe storage, including any incompatibilities

^{Storage conditions :}Store only where temperature will not exceed 125°F (52°C). Post “No Smoking/No Open Flames” signs in storage and use areas. There must be no sources of ignition. Separate packages and protect against potential fire and/or explosion damage following appropriate codes and requirements (e.g, NFPA 30, NFPA 55, NFPA 70, and/or NFPA 221 in the U.S.) or according to requirements determined by the Authority Having Jurisdiction (AHJ). Always secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand when the container is not in use. Store full and empty containers separately. Use a first-in, first-out inventory system to prevent storing full containers for long periods. For other precautions in using this product, see section 16

Acetylene, dissolved MSDS No. 101

Storage area : Acetylene trailers are designed and intended for outdoor use. Acetylene storage in excess of 2.500 cu ft (70.79 cubic meters) is prohibited in buildings and other occupancies.

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Acetylene, dissolved (74-86-2)
ACGIH	Not established
USA OSHA	Not established

8.2. Exposure controls

Eye protection : Wear safety glasses with side shields.

Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.

Environmental exposure controls : Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment.

Other information : Consider the use of flame resistant anti-static safety clothing. Wear leather safety gloves and safety shoes when handling cylinders.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 26 g/mol

Color : Colorless.

Odor : Garlic like. Poor warning properties at low concentrations.

Odor threshold : No data available

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -80.8 °C (-113.4°F)

Freezing point : No data available

Acetylene, dissolved MSDS No. 101

Boiling point : -84 °C (-119.2°F)

Flash point : -17 °C (1.4°F)

Critical temperature : 36 °C (97°F)

Auto-ignition temperature : 305 °C (581°F)

Decomposition temperature : 635 °C (1175°F)

Flammability (solid, gas) : 2.5 - 100 vol %

Vapor pressure : 44 bar (623 psig)

Critical pressure : 61.38 bar (875 psig)

Relative vapor density at 20 °C : No data available

Relative density : Not applicable.

Density : 0.0012 g/cm?3; (at 0 °C)

Relative gas density : 0.9

Solubility : Water: 1185 mg/l

Log Pow : 0.37

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None.

Explosion limits : No data available

9.2. Other information

Sublimation point : -83.3 °C

Gas group : Dissolved gas

SECTION 10: Stability and reactivity

10.1. Reactivity

No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability

Dissolved in a solvent supported in a porous mass. Stable under recommended handling and storage conditions (see section 7).

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

High temperature. High pressure. Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

10.5. Incompatible materials

Forms explosive acetylides with copper, silver and mercury. Do not use alloys containing more than 65% copper. Air, Oxidizer. Do not use alloys containing more than 43% silver.

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

pH: Not Applicable

Serious eye damage/irritation : Not classified

pH: Not Applicable

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general		:	No known ecological damage caused by this product.
12.2. Persistence and degradability
Acetylene, dissolved (74-86-2)
Persistence and degradability			Will rapidly degrade by indirect photolysis in air. Will not undergo hydrolysis.
12.3. Bioaccumulative potential
	Acetylene, dissolved (74-86-2)
	Log Pow			0.37
	Log Kow			Not applicable.
	Bioaccumulative potential			Not expected to bioaccumulate due to the low log Kow (log Kow < 4>

12.4. Mobility in soil

Acetylene, dissolved (74-86-2)
Mobility in soil	No data available.
Ecology - soil	Because of its high volatility, the product is unlikely to cause ground or water pollution.

12.5. Other adverse effects

Effect on ozone layer : No known effects from this product

Effect on the global warming : No known effects from this product

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1001 Acetylene, dissolved, 2.1

UN-No.(DOT) : UN1001

Proper Shipping Name (DOT) : Acetylene, dissolved

Hazard labels (DOT) : 2.1 - Flammable gas

Additional information

Emergency Response Guide (ERG)

Number : 116 (UN1001)

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's_:compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or^:plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Acetylene, dissolved MSDS No. 101

Transport by sea

UN-No. (IMDG) : 1001

Proper Shipping Name (IMDG) : Acetylene, dissolved

Class (IMDG) : 2 - Gases

MFAG-No : 116

Air transport

UN-No. (IATA) : 1001

Proper Shipping Name (IATA) : Acetylene, dissolved

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases flammable under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations

Acetylene, dissolved (74-86-2)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

SARA Section 311/312 Hazard Classes

Sudden release of pressure hazard

Reactive hazard

Fire hazard

All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

15.2. International regulations

CANADA

Acetylene, dissolved (74-86-2)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Acetylene, dissolved (74-86-2)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Acetylene, dissolved (74-86-2)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory

Listed on the Korean ECL (Existing Chemicals List)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)

Listed on the Canadian IDL (Ingredient Disclosure List)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

Listed on CICR (Turkish Inventory and Control of Chemicals)

15.2.2. National regulations

- Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .

- Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .

- Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.

- SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

15.3. US State regulations

Acetylene, dissolved (74-86-2)
U.S. - California - Proposition 65 - Carcinogens List	No
U.S. - California - Proposition 65 - Developmental Toxicity	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Female	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Male	No
State or local regulations	U.S - Massachusetts - Right To Know List U.S - New Jersey-Right to Know Hazard Substance List U.S - Pennsylvania - RTK (Right to Know) List

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard

beyond that of ordinary combustible materials.

NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure

and temperature, or is readily dispersed in air and will burn readily.

NFPA reactivity : 2 - Normally unstable and readily undergo violent

decomposition but do not detonate. Also: may react violently with water or may form potentially explosive mixtures with water. HMIS III Rating

Health 2 Moderate Hazard - Temporary or minor injury may occur

Flammability 4 Severe Hazard

Physical 2 Moderate Hazard

ARGON MIX

CO?2; 25 %
Argon Balance
Pressure 150 BAR
Vol 6.6 M?3;
Valve BS 341-3

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

INDUSTRI GAS ACETYLENE - OXYGEN - NITROGEN - ARGON - DLL

MATERIAL SAFETY DATA SHEETS (MSDS)

Mixgas (Argon Balance, Carbon Dioxide >5%, Oxygen 0.1 - 10%) MSDS No. 104

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Mixgas

Name : Mixgas (Argon Balance, Carbon Dioxide >5%, Oxygen 0.1 - 10%)

Other means of identification : Stargon Gas Blends Robostar CS

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Electric Arc Welding Industrial use

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification Compressed gas

H280

2.2. Label elements

GHS-US labeling	:
Hazard pictograms (GHS-US)		GHS04
Signal word (GHS-US)	:	WARNING
Hazard statements (GHS-US)	:	H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION CGA-HG03 - MAY INCREASE RESPIRATION AND HEART RATE
Precautionary statements (GHS-US)	:	P202 - Do not handle until all safety precautions have been read and understood P261 - Avoid breathing gas, vapors P262 - Do not get in eyes, on skin, or on clothing P271+P403 - Use and store only outdoors or in a well-ventilated place CGA-PG05 - Use a back flow preventive device in the piping CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG06 - Close valve after each use and when empty CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3. Other hazards

Other hazards not contributing to

Asphyxiant in high concentrations

the classification

Welding-specific: For unique hazards specific to welding, see Sections 8.2, 10.6, and 16.

2.4. Unknown acute toxicity (GHS US

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Name	Product identifier	%
Argon	(CAS No) 7440-37-1	95 - 99
Oxygen	(CAS No) 7782-44-7	0.1 - 10
Carbon dioxide	(CAS No) 124-38-9	> 5

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. If breathing is difficult, trained personnel should give oxygen. Call a physician.

^{First-aid measures after skin contact :}Wash with plenty of soap and water. For exposure, immediately warm frostbite area with warm water not to exceed 105°F (41°C). Water temperature should be tolerable to normal skin. Maintain skin warming for at least 15 minutes or until normal coloring and sensation have returned to the affected area. In case of massive exposure, remove clothing while showering with warm water. Seek medical evaluation and treatment as soon as possible.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Firefighting instructions : WARNING: High-pressure gas.

Compressed gas: asphyxiant

Suffocation hazard by lack of oxygen

Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA) and protective clothing. Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart L—Fire Protection.

Special protective equipment for : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fire fighters ^fighters.

Other information : Containers are equipped with a pressure relief device. (Exceptions may exist where authorized by DOT.).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : WARNING: High-pressure gas. Evacuate personnel to a safe area. Appropriate selfcontained breathing apparatus may be required. Approach suspected leak area with caution. Remove all sources of ignition. if safe to do so. Reduce gas with fog or fine water spray. Stop flow of product if safe to do so. Ventilate area or move container to a well-ventilated area. Before entering the area, especially a confined area, check the area with an appropriate device.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Try to stop release.

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling :

7.2. Conditions for safe storage, including any incompatibilities

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Argon (7440-37-1)
ACGIH	Not established
USA OSHA	Not established
Carbon dioxide (124-38-9)
ACGIH	ACGIH TLV-TWA (ppm)	5000 ppm
ACGIH	ACGIH TLV-STEL (ppm)	30000 ppm
USA OSHA	OSHA PEL (TWA) (mg/m?3;)	9000 mg/m?3;
USA OSHA	OSHA PEL (TWA) (ppm)	5000 ppm
Oxygen (7782-44-7)
ACGIH	Not established
USA OSHA	Not established

8.2. Exposure controls

Appropriate engineering controls : Use a local exhaust system with sufficient flow velocity to maintain an adequate supply of air in the worker's breathing zone.

Mechanical (general) : General exhaust ventilation may be acceptable if it can maintain an adequate supply of air. Ensure exposure is below occupational exposure limits (where available).

Hand protection : Wear work gloves when handling containers; welding gloves for welding. Gloves must be free of oil and grease.

Eye protection : Wear safety glasses with side shields. Wear work gloves and metatarsal shoes for cylinder handling. Protective equipment where needed. Select in accordance with OSHA 29 CFR 1910.132, 1910.136, and 1910.138. As needed for welding, wear hand, head, and body protection to help prevent injury from radiation and sparks. (See ANSI Z49.1.) At a minimum, this includes welder’s gloves and protective goggles, and may include arm protectors, aprons, hats, and shoulder protection as well as substantial clothing.

Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Color : Colorless.

Odor : Odorless.

Odor threshold : No data available

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : Not applicable.

Relative vapor density at 20 °C : No data available

Relative density : No data available

Density : 1.166 - 1.275 kg/m?3; HeliStar SS: 1.166 kg/m3 (0.0728 lb/ft3) , HeliStarCS: 1.275 kg/m3 (0.0796 lb/ft3)

Relative gas density : 0.962 - 1.062 HeliStar SS: 0.972, HeliStar CS: 1.062

Solubility : Water: No data available

Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None.

Explosion limits : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

No additional information available

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No additional information available

10.4. Conditions to avoid

No additional information available

10.5. Incompatible materials

Alkali metals, Alkaline earth metals, Acetylide forming metals, Chromium, Titanium > 1022°F (550°C), Uranium (U) > 1382°F (750°C), Magnesium > 1427°F (775°C).

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified pH: Not applicable.

Serious eye damage/irritation : Not classified pH: Not applicable.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Mixgas
Persistence and degradability	No ecological damage caused by this product.
Argon (7440-37-1)
Persistence and degradability	No ecological damage caused by this product.
Carbon dioxide (124-38-9)
Persistence and degradability	No ecological damage caused by this product.
Oxygen (7782-44-7)
Persistence and degradability	No ecological damage caused by this product.

12.3. Bioaccumulative potential

Mixgas
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.
Argon (7440-37-1)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.
Carbon dioxide (124-38-9)
BCF fish 1	(no bioaccumulation)
Log Pow	0.83
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.
Oxygen (7782-44-7)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

12.4. Mobility in soil

Mixgas
Mobility in soil	No data available.
Argon (7440-37-1)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.
Carbon dioxide (124-38-9)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.
Oxygen (7782-44-7)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.

12.5. Other adverse effects

Effect on ozone layer : None

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1956 Compressed gas, n.o.s., 2.2

UN-No.(DOT) : UN1956

Proper Shipping Name (DOT) : Compressed gas, n.o.s.

Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115

Hazard labels (DOT) : 2.2 - Non-flammable gas

DOT Symbols : G - Identifies proper shipping name (PSN) requiring the addition of technical name(s) in parentheses following the PSN

Additional information

Emergency Response Guide (ERG) : 121 (UN1006);120 (UN1951) Number

Other information : No supplementary information available.

Transport by sea

UN-No. (IMDG) : 1956

Proper Shipping Name (IMDG) : COMPRESSED GAS, N.O.S.

Class (IMDG) : 2 - Gases

Air transport

UN-No. (IATA) : 1956

Proper Shipping Name (IATA) : Compressed gas, n.o.s.

Class (IATA) : 2

SECTION 15: Regulatory information

15.1. US Federal regulations

Argon (7440-37-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes	Sudden release of pressure hazard
	Immediate (acute) health hazard

All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

15.2. International regulations

CANADA

Argon (7440-37-1)

Listed on the Canadian DSL (Domestic Substances List)

Carbon dioxide (124-38-9)

Listed on the Canadian DSL (Domestic Substances List)

Oxygen (7782-44-7)

Listed on the Canadian DSL (Domestic Substances List)

15.2.2. National regulations

Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .
Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .
Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.
SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

SECTION 16: Other information

Fumes and gases produced during welding and cutting processes can be dangerous to your health and may cause serious lung disease. KEEP YOUR HEAD OUT OF FUMES. DO NOT BREATHE FUMES AND GASES. Use enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone and the general area. Short-term overexposure to fumes may cause dizziness, nausea, and dryness or irritation of the nose, throat, and eyes; or may cause other similar discomfort. Contaminants in the air may add to the hazard of fumes and gases. One such contaminant, chlorinated hydrocarbon vapors from cleaning and degreasing activities, poses a special risk. DO NOT USE ELECTRIC ARCS IN THE PRESENCE OF CHLORINATED HYDROCARBON VAPORS—HIGHLY TOXIC PHOSGENE MAY BE PRODUCED. Metal coatings such as paint, plating, or galvanizing may generate harmful fumes when heated. Residues from cleaning materials may also be harmful. AVOID ARC OPERATIONS ON PARTS WITH PHOSPHATE RESIDUES (ANTIRUST, CLEANING PREPARATIONS)—HIGHLY TOXIC PHOSPHINE MAY BE PRODUCED

Center (Phone: 0542 - 743555; Address: SBMA Call Center, Jl Mulawarman KM 18 RT 24 No 70 Balikpapan - Kalimantan Timur, Indonesia)

NFPA health hazard : 1 - Exposure could cause irritation but only minor

residual injury even if no treatment is given.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

HMIS III Rating

Health 1 Slight Hazard - Irritation or minor reversible injury possible

Flammability 0 Minimal Hazard

Physical 3 Serious Hazard

CO² (CARBON DIOXIDA)

Purity 99.5 %
Mass 25 Kg
Valve BS341-3

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

INDUSTRI GAS ACETYLENE - OXYGEN - NITROGEN - ARGON - DLL

MATERIAL SAFETY DATA SHEETS (MSDS)

Carbon Dioxide MSDS No:108

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Carbon dioxide

CAS No : 124-38-9

Formula : CO?

Other means of identification : Medipure® Carbon Dioxide, Extendapak® EX-2, Refrigerant gas R744, carbonic anhydride, carbonic acid gas

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use. Use as directed.

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification

Liequefied gas H280

2.2. Label elements

GHS-US labeling	:
Hazard pictograms (GHS-US)		GHS04
Signal word (GHS-US)	:	WARNING
Hazard statements (GHS-US)	:	H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION CGA-HG01 - MAY CAUSE FROSTBITE CGA-HG03 - MAY INCREASE RESPIRATION AND HEART RATE
Precautionary statements (GHS-US)	:	P202 - Do not handle until all safety precautions have been read and understood P261 - Avoid breathing gas P262 - Do not get in eyes, on skin, or on clothing P271+P403 - Use and store only outdoors or in a well-ventilated place CGA-PG05 - Use a back flow preventive device in the piping CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG06 - Close valve after each use and when empty CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3. Other hazards

Other hazards not contributing to : Asphyxiant in high concentrations the classification

Contact with liquid may cause cold burns/frostbite

WARNING: Concentration levels of carbon dioxide above about 1 percent are dangerous. Praxair recommends continuous monitoring with alarms to indicate unsafe conditions before and during potential personnel exposure. Use appropriate monitoring devices to ensure a safe oxygen level (minimum of 19.5 percent) and a safe carbon dioxide level.

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name	:	Carbon dioxide
CAS No	:	124-38-9
Name		Product identifier	%
Carbon dioxide		(CAS No) 124-38-9	99.5 - 100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation :

Remove to fresh air and keep at rest in a position comfortable for breathing. . If not breathing, give artificial respiration, with supplemental oxygen given by qualified personnel. If breathing is difficult, qualified personnel should give oxygen. Call a physician.

^{First-aid measures after skin contact :}MAY CAUSE FROSTBITE. For exposure to liquid, cold vapor, or solid carbon dioxide (dry ice), immediately warm frostbite area with warm water not to exceed 41°C (105°F). Water temperature should be tolerable to normal skin. Maintain skin warming for at least 15 minutes or until normal coloring and sensation have returned to the affected area. In case of massive exposure, remove clothing while showering with warm water. Seek medical evaluation and treatment as soon as possible.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixture

Explosion hazard :

Heat of fire can build pressure in container and cause it to rupture. Containers are equipped with a pressure relief device. (Exceptions may exist where authorized by DOT.) No part of the container should be subjected to a temperature higher than 125°F (52°C).

Reactivity : No reactivity hazard other than the effects described in sub-sections below

5.3. Advice for firefighters

Firefighting instructions : WARNING! Liquid and gas under pressure.

Other information : Containers are equipped with a pressure relief device. (Exceptions may exist where authorized by DOT [U.S.] or TC [Canada].).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures

WARNING! Liquid and gas under pressure.. Rapid release of gaseous carbon dioxide through a pressure relief device (PRD) or valve can result in the formation of dry ice, which is very cold and can cause frostbite.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Try to stop release.

6.3. Methods and material for containment and cleaning up

For containment : Prevent waste from contaminating the surrounding environment. Discard any product, residue, disposable container, or liner in an environmentally acceptable manner, in full compliance with federal, provincial, and local regulations. If necessary, call your local supplier for assistance.

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid breathing gas

Do not get in eyes, on skin, or on clothing

This gas is heavier than air and in an enclosed space tends to accumulate near the floor, displacing air and pushing it upward. This creates an oxygen-deficient atmosphere near the floor. Ventilate space before entry. Verify sufficient oxygen concentration

WARNING: Concentration levels of carbon dioxide above about 1 percent are dangerous. SBMA recommends continuous monitoring with alarms to indicate unsafe conditions before and during potential personnel exposure. Use appropriate monitoring devices to ensure a safe oxygen level (minimum of 19.5 percent) and a safe carbon dioxide level

7.2. Conditions for safe storage, including any incompatibilities

^{Storage conditions :}Store in a cool, well-ventilated place. Store and use with adequate ventilation. Store only where temperature will not exceed 125°F (52°C). Firmly secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand. Store full and empty containers separately. Use a first-in, first-out inventory system to prevent storing full containers for long periods

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Carbon dioxide (124-38-9)
ACGIH	ACGIH TLV-TWA (ppm)	5000 ppm
ACGIH	ACGIH TLV-STEL (ppm)	30000 ppm
USA OSHA	OSHA PEL (TWA) (mg/m?3;)	9000 mg/m?3;
USA OSHA	OSHA PEL (TWA) (ppm)	5000 ppm
USA IDLH	US IDLH (ppm)	40000 ppm
ACGIH	Not established
USA OSHA	Not established
Carbon dioxide (124-38-9)
ACGIH	ACGIH TLV-TWA (ppm)	5000 ppm
ACGIH	ACGIH TLV-STEL (ppm)	30000 ppm
USA OSHA	OSHA PEL (TWA) (mg/m?3;)	9000 mg/m?3;
USA OSHA	OSHA PEL (TWA) (ppm)	5000 ppm

8.2. Exposure controls

Appropriate engineering controls :

Use a local exhaust system with sufficient flow velocity to maintain an adequate supply of air in the worker's breathing zone. Mechanical (general): General exhaust ventilation may be acceptable if it can maintain an adequate supply of air. WARNING: Concentration levels of carbon dioxide above about 1 percent are dangerous. Praxair recommends continuous monitoring with alarms to indicate unsafe conditions before and during potential personnel exposure. Use appropriate monitoring devices to ensure a safe oxygen level (minimum of 19.5 percent) and a safe carbon dioxide level.

Materials for protective clothing : Wear work gloves and metatarsal shoes for cylinder handling. Protective equipment where needed. Select in accordance with OSHA 29 CFR 1910.132, 1910.136, and 1910.138.

Eye protection : Wear safety glasses when handling cylinders; vapor-proof goggles and a face shield during cylinder changeout or whenever contact with product is possible. Select eye protection in accordance with OSHA 29 CFR 1910.133.

Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 44 g/mol

Color : Colorless.

Odor : Odorless.

Odor threshold : No data available

pH : 3.7 (carbonic acid)

Relative evaporation rate (butyl acetate=1) No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : No data available

Freezing point : No data available

Boiling point : -78.5 °C (-109.3°F)

Flash point : No data available

Critical temperature : 31 °C (87.7°F)

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : 57.3 bar (831 psig)

Critical pressure : 73.7 bar (1069 psig)

Relative vapor density at 20 °C : 762

Relative density : 1.22

Relative gas density : 1.52

Solubility : Water: 2000 mg/l Completely soluble.

Log Pow : 0.83

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None.

Explosion limits : No data available

9.2. Other information

Gas group : Liquefied gas

Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground level

SECTION 10: Stability and reactivity

10.1. Reactivity

No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

None.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

Alkali metals, Alkaline earth metals, Acetylide forming metals, Chromium, Titanium > 1022°F (550°C), Uranium (U) > 1382°F (750°C), Magnesium > 1427°F (775°C).

10.6. Hazardous decomposition products

Electrical discharges and high temperatures decompose carbon dioxide into carbon monoxide and oxygen. The welding process may generate hazardous fumes and gases.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified pH: 3.7 (carbonic acid)

Serious eye damage/irritation : Not classified pH: 3.7 (carbonic acid)

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Carbon dioxide (124-38-9)
Persistence and degradability	No ecological damage caused by this product.
Carbon dioxide (124-38-9)
Persistence and degradability	No ecological damage caused by this product.

12.3. Bioaccumulative potential

Carbon dioxide (124-38-9)
BCF fish 1	(no bioaccumulation)
Log Pow	0.83
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.
Carbon dioxide (124-38-9)
BCF fish 1	(no bioaccumulation)
Log Pow	0.83
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

12.4. Mobility in soil

Carbon dioxide (124-38-9)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.
Carbon dioxide (124-38-9)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.

12.5. Other adverse effects

Effect on ozone layer : None

Global warming potential [CO2=1] : 1

Effect on the global warming : When discharged in large quantities may contribute to the greenhouse effect

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : May be vented to atmosphere in a well ventilated place. Discharge to atmosphere in large quantities should be avoided. Do not discharge into any place where its accumulation could be dangerous. Contact supplier if guidance is required.

Waste disposal recommendations : Do not attempt to dispose of residual or unused quantities. Return container to supplier.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1013 Carbon dioxide, 2.2

UN-No.(DOT) : UN1013

Proper Shipping Name (DOT) : Carbon dioxide

Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115

Hazard labels (DOT) : 2.2 - Non-flammable gas

Additional information

Emergency Response Guide (ERG) : 120

Number

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's:compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet:cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Transport by sea

UN-No. (IMDG) : 1013

Proper Shipping Name (IMDG) : CARBON DIOXIDE

Class (IMDG) : 2 - Gases

MFAG-No : 120

Air transport

UN-No. (IATA) : 1013

Proper Shipping Name (IATA) : Carbon dioxide

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations

Carbon dioxide (124-38-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes	Immediate (acute) health hazard Sudden release of pressure hazard

15.2. International regulations

CANADA

Carbon dioxide (124-38-9)

Listed on the Canadian DSL (Domestic Substances List)

Carbon dioxide (124-38-9)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Carbon dioxide (124-38-9)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Carbon dioxide (124-38-9)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory

Listed on the Korean ECL (Existing Chemicals List)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)

Listed on the Canadian IDL (Ingredient Disclosure List)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

Listed on CICR (Turkish Inventory and Control of Chemicals)

15.2.2. National regulations

Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .- Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .
Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.

SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an industrial hygienist or other trained person when you evaluate the end product. Before using any plastics, confirm their compatibility with this product Fumes and gases produced during welding and cutting processes can be dangerous to your health and may cause serious lung disease. KEEP YOUR HEAD OUT OF FUMES. DO NOT BREATHE FUMES AND GASES. Use enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone and the general area. Short-term overexposure to fumes may cause dizziness, nausea, and dryness or irritation of the nose, throat, and eyes; or may cause other similar discomfort. Contaminants in the air may add to the hazard of fumes and gases. One such contaminant, chlorinated hydrocarbon vapors from cleaning and degreasing activities, poses a special risk. DO NOT USE ELECTRIC ARCS IN THE PRESENCE OF CHLORINATED HYDROCARBON VAPORS—HIGHLY TOXIC PHOSGENE MAY BE PRODUCED. Metal coatings such as paint, plating, or galvanizing may generate harmful fumes when heated. Residues from cleaning materials may also be harmful. AVOID ARC OPERATIONS ON PARTS WITH PHOSPHATE RESIDUES (ANTI-RUST, CLEANING PREPARATIONS)—HIGHLY TOXIC PHOSPHINE MAY BE PRODUCED The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and the conditions of use are not within the control of Praxair, Inc, it is the user's obligation to determine the conditions of safe use of the product SBMA SDSs are furnished on sale or delivery by SBMA or the independent distributors and suppliers who package and sell our products. To obtain current SDSs for these products, contact your SBMA sales representative, local distributor, or supplier, would like the document number and date of the latest SDS, or would like the names of the SBMA suppliers in your area, phone or write the SBMA Call Center (Phone: (0542) - 743555 Address:SBMA Call Center, Jl. Mulawarman KM 18 RT 24 No 70 Batakan - Kaltim) SBMA asks users of this product to study this SDS and become aware of the product hazards and safety information. To promote safe use of this product, a user should (1) notify employees, agents, and contractors of the information in this SDS and of any other known product hazards and safety information, (2) furnish this information to each purchaser of the product, and (3) ask each purchaser to notify its employees and customers of the product hazards and safety information SBMA, the Flowing Airstream design, Medipure, and the Medipure design are trademarks or registered trademarks of SURYA BIRU MURNI ACETYLENE.

NFPA health hazard : 2 - Intense or continued exposure could cause temporary

incapacitation or possible residual injury unless prompt medical attention is given.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water.

NFPA specific hazard : SA - This denotes gases which are simple asphyxiants.

HMIS III Rating

Health 1 Slight Hazard - Irritation or minor reversible injury possible

Flammability 0 Minimal Hazard

Physical 3 Serious Hazard

N² HP

Purity 99.995 %
Pressure 150 BAR
H?2;O < 5> O?2; < 10> CnHm < 3> Vol 5.8 M?3;
Valve BS 341-3

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

MATERIAL SAFETY DATA SHEETS (MSDS)

Nitrogen, compressed MSDS No. 110

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Nitrogen, compressed

CAS No : 7727-37-9

Formula : N?

Other means of identification : Dinitrogen, Refrigerant R728, Nitrogen, Medipure Nitrogen, Extendapak Nitrogen, Nitrogen - Diving Grade

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use

Medical applications.

Food applications.

Diving Gas (Underwater Breathing)

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification Compressed gas 2.2. Label elements	H280
GHS-US labeling	:
Hazard pictograms (GHS-US)		GHS04
Signal word (GHS-US)	:	WARNING
Hazard statements (GHS-US)	:	H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
Precautionary statements (GHS-US)	:	P202 - Do not handle until all safety precautions have been read and understood P271+P403 - Use and store only outdoors or in a well-ventilated place. CGA-PG05 - Use a back flow preventive device in the piping. CGA-PG10 - Use only with equipment rated for cylinder pressure. CGA-PG06 - Close valve after each use and when empty. CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F).

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity (GHS - US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name	:	Nitrogen, compressed
CAS No	:	7727-37-9
Name		Product identifier	%
Nitrogen		(CAS No) 7727-37-9	99.5 - 100

Nitrogen, compressed MSDS No. 110

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Immediately remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, qualified personnel may give oxygen. Call a physician.

First-aid measures after skin contact : Adverse effects not expected from this product.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixture

Reactivity : Under certain conditions, nitrogen can react violently with lithium, neodymium, titanium (above 1472°F/800°C), and magnesium to form nitrides. At high temperature, it can also combine with oxygen and hydrogen.

5.3. Advice for firefighters

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.

Special protective equipment for : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fire fighters ^fighters.

Stop flow of product if safe to do so.

Use water spray or fog to knock down fire fumes if possible.

SECTION 6: Accidental release measures

General measures : Evacuate area. Ensure adequate air ventilation. Wear self-contained breathing apparatus when entering area unless atmosphere is proven to be safe. Stop leak if safe to do so.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

No additional information available

SECTION 6: Accidental release measures

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Never insert an object (e.g., wrench, screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to open, discontinue use and contact your supplier. Close the container valve after each use; keep closed even when empty. Never apply flame or localized heat directly to any part of the container. High temperatures may damage the container and could cause the pressure relief device to fail prematurely, venting the container contents. For other precautions in using this product, see section 16.

7.2. Conditions for safe storage, including any incompatibilities

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container here it may become part of an electrical circuit.

7.3. Specific end use(s)

None

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Nitrogen, compressed (7727-37-9)
ACGIH	Not established
USA OSHA	Not established
Nitrogen (7727-37-9)
ACGIH	Not established
USA OSHA	Not established

Nitrogen, compressed MSDS No. 110

8.2. Exposure controls

Eye protection : Wear safety glasses with side

Respiratory protection :

When workplace conditions warrant respirator use, follow a respiratory protection program that meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable). Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the respirator has the appropriate protection factor for the exposure level. If cartridge type respirators are used, the cartridge must be appropriate for the chemical exposure (e.g., an organic vapor cartridge). For emergencies or instances with unknown exposure levels, use a self-contained breathing apparatus (SCBA).

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 28 g/mol

Color : Colorless.

Odor : No odor warning properties.

Odor threshold : No data available

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -210 °C

Freezing point : No data available

Boiling point : -195.8 °C

Flash point : No data available

Critical temperature : -149.9 °C

Auto-ignition temperature : Not applicable.

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : Not applicable.

Critical pressure : 3390 kPa

Relative vapor density at 20 °C : No data available

Relative density : No data available

Density : 1.16 kg/m?3;

Relative gas density : 0.97

Solubility : Water: 20 mg/l

Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None

Explosion limits : No data available

9.2. Other information

Gas group : Compressed gas

Additional information : None

SECTION 10: Stability and reactivity

10.1. Reactivity

No additional information available

Under certain conditions, nitrogen can react violently with lithium, neodymium, titanium (above 1472°F/800°C), and magnesium to form nitrides. At high temperature, it can also combine with oxygen and hydrogen.

10.2. Chemical stability

Stable under normal conditions

10.3. Possibility of hazardous reactions

May occur.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

None.

10.6. Hazardous decomposition products

None

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

pH : Not applicable.

Serious eye damage/irritation : Not classified

pH : Not applicable.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Nitrogen, compressed (7727-37-9)
Persistence and degradability	No ecological damage caused by this product.
Nitrogen (7727-37-9)
Persistence and degradability	No ecological damage caused by this product.

12.3. Bioaccumulative potential

Nitrogen (7727-37-9)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.
Nitrogen (7727-37-9)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Nitrogen, compressed (7727-37-9)
Persistence and degradability	No ecological damage caused by this product.
Nitrogen (7727-37-9)
Persistence and degradability	No ecological damage caused by this product.

12.3. Bioaccumulative potential

Nitrogen (7727-37-9)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.
Nitrogen (7727-37-9)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

In accordance with DOT

Transport document description : UN1066 Nitrogen, compressed, 2.2

UN-No.(DOT) : UN1066

Proper Shipping Name (DOT) : Nitrogen, compressed

Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115

Other information : No supplementary information available.

Transport by sea

UN-No. (IMDG) : 1066

Proper Shipping Name (IMDG) : NITROGEN, COMPRESSED

Class (IMDG) : 2 - Gases

MFAG-No : 121

Air transport

UN-No. (IATA) : 1066

Proper Shipping Name (IATA) : Nitrogen, compressed

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations

Nitrogen, compressed (7727-37-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes	Sudden release of pressure hazard

15.2. International regulations

CANADA

Nitrogen, compressed (7727-37-9)

Listed on the Canadian DSL (Domestic Substances List)

Nitrogen (7727-37-9)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Nitrogen, compressed (7727-37-9)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Nitrogen, compressed (7727-37-9)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Korean ECL (Existing Chemicals List)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)

15.2.2. National regulations

- Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .

- Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .

- Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.

- SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

15.3. US State regulations

Nitrogen, compressed(7727-37-9)
U.S. - California - Proposition 65 - Carcinogens List	No
U.S. - California - Proposition 65 - Developmental Toxicity	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Female	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Male	No
State or local regulations	U.S - Massachusetts - Right To Know List U.S - New Jersey-Right to Know Hazard Substance List U.S - Pennsylvania - RTK (Right to Know) List

SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards.

NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard

beyond that of ordinary combustible materials.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water.

NFPA specific hazard : SA - This denotes gases which are simple asphyxiants.

HMIS III Rating

Health 0 Minimal Hazard - No significant risk to health

Flammability 0 Minimal Hazard

Physical 3 Serious Hazard

N² UHP

Purity 99.995 %
Pressure 200 BAR
H?2;O < 2> O?2; < 3> CnHm < 1> Vol 9.5 M?3;
Valve BS 341-3

MSDS & SPECIFICATION

PT. SURYA BIRU MURNI ACETYLENE

MATERIAL SAFETY DATA SHEETS (MSDS)

Helium, compressed MSDS No. 106

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Subtance

Name : Helium, compressed

CAS No : 7440-59-7

Formula : He

Other means of identification : Helium-4, refrigerant gas R-704, LaserStar Helium, Medipure Helium, UltraLift Helium, Helium - Diving Grade

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use

Medical applications

Diving Gas (Underwater Breathing)

1.3. Details of the supplier of the safety data sheet

: PT. SURYA BIRU MURNI ACETYLENE

Jl. Mulawarman Km 18 RT 24 No 70 Balikpapan - Kalimantan Timur

Telp : (0542) - 743555, Fax : (0542) - 763200

Email : marketing@suryabiru.co.id

1.4. Emergency telephone number

: 08125362500 (After Hours)

'085347225644

Telp : (0542) - 743555 (In Hours)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification Compressed gas 2.2. Label elements	H280
GHS-US labeling	:
Hazard pictograms (GHS-US)		GHS04
Signal word (GHS-US)	:	WARNING
Hazard statements (GHS-US)	:	H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
Precautionary statements (GHS-US)	:	P202 - Do not handle until all safety precautions have been read and understood P271 - Use and store only outdoors or in a well-ventilated area P403 - Use and store only outdoors or in a well-ventilated place CGA-PG05 - Use a back flow preventive device in the piping CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG06 - Close valve after each use and when empty CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3. Other hazards

Other hazards not contributing to : Asphyxiant in high concentrations.

the classification

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name : Helium, compressed

CAS No : 7440-59-7

Helium, compressed MSDS No. 106

Name	Product identifier	%
Helium	(CAS No) 7440-59-7	99.5 - 100

3.2. Mixture

Not Applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation :

First-aid measures after skin contact : Adverse effects not expected from this product.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

None

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.

Special protective equipment for : Use self-contained breathing apparatus. Standard protective clothing and equipment (Self _{fire fighters}Contained Breathing Apparatus) for fire fighters.

Stop flow of product if safe to do so

Use water spray or fog to knock down fire fumes if possible.

Helium, compressed MSDS No. 106

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Evacuate area. Ensure adequate air ventilation. Wear self-contained breathing apparatus when entering area unless atmosphere is proven to be safe. Stop leak if safe to do so.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Try to stop release.

6.3. Methods and material for containment and cleaning up

No additional information available

6.4. Reference to other sections

See also sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

7.3. Specific end use(s)

None

Helium, compressed MSDS No. 106

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Helium, compressed (7440-59-7)
ACGIH	Not established
USA OSHA	Not established
Helium, compressed (7440-59-7)
ACGIH	Not established
USA OSHA	Not established

8.2. Exposure controls

Eye protection : Wear safety glasses with side shields.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Colorless gas.

Molecular mass : 4 g/mol

Color : Colorless.

Odor : Odorless.

Odor threshold : No data available

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -272 °C

Freezing point : No data available

Boiling point : -268.93 °C

Flash point : No data available

Critical temperature : -268 °C

Auto-ignition temperature : Not applicable.

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : Not applicable.

Critical pressure : 230 kPa

Relative vapor density at 20 °C : No data available

Relative density : No data available

Density : 0.166 kg/m?3;

Relative gas density : 0.14

Solubility : Water: 1.5 mg/l

Helium, compressed MSDS No. 106

Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : None.

Explosion limits : No data available

9.2. Other information

Gas group : Compressed gas

Additional information : None

SECTION 10: Stability and reactivity

10.1. Reactivity

No additional information available

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

None.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

None

10.6. Hazardous decomposition products

None

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified pH: Not applicable.

Serious eye damage/irritation : Not classified pH: Not applicable.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

12.1. Toxicity

Ecology - general : No ecological damage caused by this product.

12.2. Persistence and degradability

Helium, compressed (7440-59-7)
Persistence and degradability	No ecological damage caused by this product.
Helium, compressed (7440-59-7)
Persistence and degradability	No ecological damage caused by this product.

12.3. Bioaccumulative potential

Helium, compressed (7440-59-7)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

Helium, compressed MSDS No. 106

Helium, compressed (7440-59-7)
Log Pow	Not applicable.
Log Kow	Not applicable.
Bioaccumulative potential	No ecological damage caused by this product.

12.4. Mobility in soil

Helium, compressed (7440-59-7)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.
Helium, compressed (7440-59-7)
Mobility in soil	No data available.
Ecology - soil	No ecological damage caused by this product.

12.5. Other adverse effects

Effect on ozone layer : None

Effect on the global warming : None

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1046 Helium, compressed, 2.2

UN-No.(DOT) : UN1046

Proper Shipping Name (DOT) : Helium, compressed

Class (DOT) : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115

Other information : No supplementary information available.

Transport by sea

UN-No. (IMDG) : 1046

Proper Shipping Name (IMDG) : HELIUM, COMPRESSED

Class (IMDG) : 2 - Gases

MFAG-No : 121

Air transport

UN-No. (IATA) : 1046

Proper Shipping Name (IATA) : Helium, compressed

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases nonflammable nontoxic under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations

Helium, compressed (7440-59-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes	Sudden release of pressure hazard

All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

15.2. International regulations

CANADA

Helium, compressed (7440-59-7)

Listed on the Canadian DSL (Domestic Substances List)

Helium, compressed (7440-59-7)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

Helium, compressed (7440-59-7)

Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Helium, compressed (7440-59-7)

Listed on the AICS (Australian Inventory of Chemical Substances)

Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)

Listed on the Korean ECL (Existing Chemicals List)

Listed on NZIoC (New Zealand Inventory of Chemicals)

Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

15.2.2. National regulations

- Kepmenaker RI NO. Kep 187/Men/1999 tentang Pengendalian Bahan Kimia Berbahaya .

- Undang - Undang RI No.23 Tahun 1997 tentang Pengelolaan Lingkungan hidup .

- Permen No. 85 Tahun 1999 tentang perubahan atas permen No. 18 Tahun 1999 tentang Pengelolaan Limbah BahanBerbahaya dan Beracun.

- Kepmenaker RI No. Per-0/Men/1982 tentang pelayanan penyelengaraan Kesehatan Tenaga Kerja.

- SE/06/Men/1990 tentang Pewarnaan Bejan Bertekanan.

15.3. US State regulations

Helium, compressed (7440-59-7)
U.S. - California - Proposition 65 - Carcinogens List	No
U.S. - California - Proposition 65 - Developmental Toxicity	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Female	No
U.S. - California - Proposition 65 - Reproductive Toxicity - Male	No
State or local regulations	U.S - Massachusetts - Right To Know List U.S - New Jersey-Right to Know Hazard Substance List U.S - Pennsylvania - RTK (Right to Know) List

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards.

NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

NFPA specific hazard : SA - This denotes gases which are simple asphyxiants.

HMIS III Rating

Health 0 Minimal Hazard - No significant risk to health

Flammability 0 Minimal Hazard

Physical 3 Serious Hazard